A Study of the Catalytic Steam Cracking of Heavy Crude Oil in the Presence of a Dispersed Molybdenum-Containing Catalyst

被引:18
作者
Mironenko, O. O. [1 ]
Sosnin, G. A. [1 ,2 ]
Eletskii, P. M. [1 ]
Gulyaeva, Yu. K. [1 ]
Bulavchenko, O. A. [1 ,2 ]
Stonkus, O. A. [1 ,2 ]
Rodina, V. O. [1 ]
Yakovlev, V. A. [1 ]
机构
[1] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
基金
俄罗斯科学基金会;
关键词
dispersed catalyst; molybdenum; heavy crude oil; catalytic steam cracking; NATURAL BITUMEN; AQUATHERMOLYSIS; HYDROCONVERSION; NANOPARTICLES; FEEDSTOCK; VISCOSITY;
D O I
10.1134/S0965544117070088
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The features of the steam cracking of heavy crude oil in the presence of a dispersed molybdenum-containing catalyst are studied. The effect of water, the catalyst, and process conditions on the composition and properties of the products of the thermal conversion of heavy crude oil is determined in experiments on thermal cracking, steam cracking, catalytic cracking in the absence of water, and hydrocracking. A complex analysis of the resulting products is conducted; the catalyst-containing solid residue (coke) has been studied by XRD and HRTEM. The effect of the process temperature (425 and 450 degrees C) and time on the yields and properties of the resulting products is studied. The efficiencies of hydrocracking and steam cracking for the production of upgraded low-viscosity semisynthetic oil are compared; the fundamental changes that occur in the catalyst during the studied processes are discussed. Some assumptions about the principle of the catalytic action of the molybdenum-containing catalyst in the steam cracking process are made.
引用
收藏
页码:618 / 629
页数:12
相关论文
共 43 条
[1]   A review of experimental procedures for heavy oil hydrocracking with dispersed catalyst [J].
Angeles, M. J. ;
Leyva, C. ;
Ancheyta, J. ;
Ramirez, S. .
CATALYSIS TODAY, 2014, 220 :274-294
[2]  
Antipenko V.R., 2006, IZV TOMSK POLITEKH U, V309, P174
[3]  
Carrazza J, 1997, US patent, Patent No. 5688395
[4]   Current situation of emerging technologies for upgrading of heavy oils [J].
Castaneda, Luis C. ;
Munoz, Jose A. D. ;
Ancheyta, Jorge .
CATALYSIS TODAY, 2014, 220 :248-273
[5]  
Clark P.D., 1990, AOSTRA J RES, V6, P53
[6]  
Desouky S, 2013, Int J Chem Mol Eng, V7, P638, DOI [doi.org/10.5281/zenodo.1086831, DOI 10.5281/ZENODO.1086831]
[7]   Investigating the process of heavy crude oil steam cracking in the presence of dispersed catalysts. II: Investigating the effect of Ni-containing catalyst concentration on the yield and properties of products [J].
Eletskii P.M. ;
Mironenko O.O. ;
Sosnin G.A. ;
Bulavchenko O.A. ;
Stonkus O.A. ;
Yakovlev V.A. .
Catalysis in Industry, 2016, 8 (04) :328-335
[8]   Investigating the process of heavy crude oil steam cracking over disperse catalysts. I: Selection of optimal steam cracking conditions without catalyst [J].
Eletskii P.M. ;
Mironenko O.O. ;
Selishcheva S.A. ;
Yakovlev V.A. .
Catalysis in Industry, 2016, 8 (03) :217-223
[9]   Production of lighter fuels by cracking petroleum residual oils with steam over zirconia-supporting iron oxide catalysts [J].
Fumoto, E ;
Tago, T ;
Masuda, T .
ENERGY & FUELS, 2006, 20 (01) :1-6
[10]   Recovery of useful hydrocarbons from petroleum residual oil by catalytic cracking with steam over zirconia-supporting iron oxide catalyst [J].
Fumoto, E ;
Tago, T ;
Tsuji, T ;
Masuda, T .
ENERGY & FUELS, 2004, 18 (06) :1770-1774