The ansa-zirconocene [bis(η5-cyclopentadienyl)phenylphosphine]dichloridozirconium(IV)

被引：0
|
作者：
Bueschel, Susanne [1 ]
Daniliuc, Constantin [1 ]
Jones, Peter G. [1 ]
Tamm, Matthias [1 ]
机构：
[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2010年 / 66卷
关键词：
COMPLEXES; ZIRCONIUM;
D O I：
10.1107/S0108270110004531
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, [Zr(C16H13P)Cl-2], the geometry at the metal atom is distorted tetrahedral; the Cl-Zr-Cl angle is 101.490 (16)degrees and the cyclopentadienyl (Cp) centroids subtend an angle of 122.63 (3)degrees at the Zr atom. The P atom lies 0.474 (3) and 0.496 (3) angstrom out of the planes of the Cp rings. The C-P-C angle of 91.42 (7)degrees reflects the pincer effect of the two Cp rings. Three C-H center dot center dot center dot Cl, one C-H center dot center dot center dot P, one C-H center dot center dot center dot pi and one Cl center dot center dot center dot P interaction link the molecules to form thick layers parallel to the bc plane.
引用
收藏
页码：M86 / M88
页数：3
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