Preparation of Hg2+ selective fluorescent chemosensors based on surface modified core-shell aluminosilicate nanoparticles

被引:12
作者
Delgado-Pinar, Estefania [1 ,2 ]
Montoya, Noemi [2 ]
Galiana, Maite [2 ]
Teresa Albelda, M. [1 ]
Frias, Juan C. [1 ]
Jimenez, Hermas R. [2 ]
Garcia-Espana, Enrique [1 ]
Alarcon, Javier [2 ]
机构
[1] Univ Valencia, Dept Quim Inorgan, ICMOL, Valencia 46071, Spain
[2] Univ Valencia, Dept Quim Inorgan, E-46100 Valencia, Spain
关键词
NANOSIZED BOEHMITE PARTICLES; ANODIC-STRIPPING VOLTAMMETRY; METAL-IONS; GOLD NANOPARTICLES; AQUEOUS-SOLUTIONS; MERCURIC ION; SENSOR; MERCURY(II); RECEPTORS; COMPLEXES;
D O I
10.1039/b9nj00590k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A synthetic procedure for the preparation of functional structured inorganic-organic hybrid materials consisting of boehmite-silica core-shell nanoparticles and anthracene-containing amines covalently attached to the nanoparticles surface is reported. The system functionalised with the monoamine chain shows a very high sensing performance for Hg2+ detection in pure water reaching a detection limit of 0.2 ppb. Two additional advantages of these systems are their stability over a wide pH window and the feasibility to be recovered by a simple procedure.
引用
收藏
页码:567 / 570
页数:4
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