Templated synthesis of CdS/PAN composite nanowires under ambient conditions

被引：28
作者：
Chen, M
Xie, Y [1 ]
Chen, HY
Qiao, ZP
Zhu, YJ
Qian, YT
机构：
[1] Univ Sci & Technol China, Struct Res Lab, Hefei 230023, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230023, Anhui, Peoples R China
来源：
JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2000年 / 229卷 / 01期
关键词：
CdS; polyacrylonitrile; nanowires; templated synthesis;
D O I：
10.1006/jcis.2000.6983
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
CdS/PAN (polyacrylonitrile) composite nanowires were prepared by templated synthesis under ambient conditions, using a 4:1 (v/v) distilled water-isopropyl alcohol solvent mixture and Na2S2O3 as sulfur source. Transmission electron microscopy images showed typical CdS/PAN nanowires with diameters less than 6 nm and lengths from 200 nm to 1 mu m. CdS/PAN nanowires were also characterized by FT-infrared spectra (FTIR), X-ray powder diffraction (XRD) patterns, and UV-vis spectra. It is found that the feed mole ratio of CdCl2 to AN exerts a significant influence on the formation and morphology of CdS/PAN nanowires. In addition, possible mechanism of the reactive process was presented. (C) 2000 Academic Press.
引用
收藏
页码：217 / 221
页数：5
相关论文
共 33 条
  • [21] RAUH DR, 1988, SEMICONDUCTOR ELECTR, pCH6
  • [22] Electrochemical fabrication of CdS nanowire arrays in porous anodic aluminum oxide templates
    Routkevitch, D
    Bigioni, T
    Moskovits, M
    Xu, JM
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (33) : 14037 - 14047
  • [23] Silverstein R.M., 1991, SPECTROSCOPIC IDENTI
  • [24] SIZE QUANTIZATION EFFECTS IN CADMIUM-SULFIDE LAYERS FORMED BY A LANGMUIR-BLODGETT TECHNIQUE
    SMOTKIN, ES
    LEE, C
    BARD, AJ
    CAMPION, A
    FOX, MA
    MALLOUK, TE
    WEBBER, SE
    WHITE, JM
    [J]. CHEMICAL PHYSICS LETTERS, 1988, 152 (2-3) : 265 - 268
  • [25] PHOTOCHEMISTRY OF COLLOIDAL SEMICONDUCTORS .20. SURFACE MODIFICATION AND STABILITY OF STRONG LUMINESCING CDS PARTICLES
    SPANHEL, L
    HAASE, M
    WELLER, H
    HENGLEIN, A
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (19) : 5649 - 5655
  • [26] COLLOIDAL SEMICONDUCTOR Q-PARTICLES - CHEMISTRY IN THE TRANSITION REGION BETWEEN SOLID-STATE AND MOLECULES
    WELLER, H
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (01): : 41 - 53
  • [27] Xie Y, 1999, ADV MATER, V11, P1512, DOI 10.1002/(SICI)1521-4095(199912)11:18<1512::AID-ADMA1512>3.0.CO
  • [28] 2-S
  • [29] A new approach to fabrication of a self-organizing film of heterostructured polymer/CdS nanoparticles
    Xiong, HM
    Zhou, Z
    Wang, ZQ
    Zhang, X
    Shen, JC
    [J]. SUPRAMOLECULAR SCIENCE, 1998, 5 (5-6): : 623 - 626
  • [30] A cluster growth route to quantum-confined CdS nanowires
    Yan, P
    Xie, Y
    Qian, YT
    Liu, XM
    [J]. CHEMICAL COMMUNICATIONS, 1999, (14) : 1293 - 1294
1234