High capacity ammonia adsorption in a robust metal-organic framework mediated by reversible host-guest interactions

被引：17

作者：

Guo, Lixia ^{[1
]}

Han, Xue ^{[1
]}

Ma, Yujie ^{[1
]}

Li, Jiangnan ^{[1
]}

Lu, Wanpeng ^{[1
]}

Li, Weiyao ^{[1
]}

Lee, Daniel ^{[2
]}

da Silva, Ivan ^{[3
]}

Cheng, Yongqiang ^{[4
]}

Rudic, Svemir ^{[3
]}

Manuel, Pascal ^{[3
]}

Frogley, Mark D. ^{[5
]}

Ramirez-Cuesta, Anibal J. ^{[4
]}

Schroder, Martin ^{[1
]}

Yang, Sihai ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[2] Univ Manchester, Dept Chem Engn & Analyt Sci, Manchester M13 9PL, Lancs, England

[3] STFC Rutherford Appleton Lab, ISIS Facil, Didcot OX11 0QX, Oxon, England

[4] Oak Ridge Natl Lab, Neutron Scattering Div, Neutron Sci Directorate, Oak Ridge, TN 37831 USA

[5] Diamond Light Source, Harwell Sci & Innovat Campus, Didcot OX11 0DE, Oxon, England

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 38期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

D O I：

10.1039/d2cc01197b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To understand the exceptional adsorption of ammonia (NH3) in MFM-300(Sc) (19.5 mmol g(-1) at 273 K and 1 bar without hysteresis), we report a systematic investigation of the mechanism of adsorption by a combination of in situ neutron powder diffraction, inelastic neutron scattering, synchrotron infrared microspectroscopy, and solid-state Sc-45 NMR spectroscopy. These complementary techniques reveal the formation of reversible host-guest supramolecular interactions, which explains directly the observed excellent reversibility of this material over 90 adsorption-desorption cycles.

引用

页码：5753 / 5756

页数：4

共 20 条

[1] Recyclable ammonia uptake of a MIL series of metal-organic frameworks with high structural stability [J].

Chen, Yang ;

Zhang, Feifei ;

Wang, Yong ;

Yang, Chengyin ;

Yang, Jiangfeng ;

Li, Jinping .

MICROPOROUS AND MESOPOROUS MATERIALS, 2018, 258 :170-177

[2] Computational Screening of Functionalized UiO-66 Materials for Selective Contaminant Removal from Air [J].

Demir, Hakan ;

Walton, Krista S. ;

Sholl, David S. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (37) :20396-20406

[3]

Doonan CJ, 2010, NAT CHEM, V2, P235, DOI [10.1038/nchem.548, 10.1038/NCHEM.548]

[4] Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework [J].

Godfrey, Harry G. W. ;

da Silva, Ivan ;

Briggs, Lydia ;

Carter, Joseph H. ;

Morris, Christopher G. ;

Savage, Mathew ;

Easun, Timothy L. ;

Manuel, Pascal ;

Murray, Claire A. ;

Tang, Chiu C. ;

Frogley, Mark D. ;

Cinque, Gianfelice ;

Yang, Sihai ;

Schroeder, Martin .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (45) :14778-14781

[5] Power of Infrared and Raman Spectroscopies to Characterize Metal-Organic Frameworks and Investigate Their Interaction with Guest Molecules [J].

Hadjiivanov, Konstantin, I ;

Panayotov, Dimitar A. ;

Mihaylov, Mihail Y. ;

Ivanova, Elena Z. ;

Chakarova, Kristina K. ;

Andonova, Stanislava M. ;

Drenchev, Nikola L. .

CHEMICAL REVIEWS, 2021, 121 (03) :1286-1424

[6] High Ammonia Adsorption in MFM-300 Materials: Dynamics and Charge Transfer in Host-Guest Binding [J].

Han, Xue ;

Lu, Wanpeng ;

Chen, Yinlin ;

da Silva, Ivan ;

Li, Jiangnan ;

Lin, Longfei ;

Li, Weiyao ;

Sheveleva, Alena M. ;

Godfrey, Harry G. W. ;

Lu, Zhenzhong ;

Tuna, Floriana ;

McInnes, Eric J. L. ;

Cheng, Yongqiang ;

Daemen, Luke L. ;

McPherson, Laura J. McCormick ;

Teat, Simon J. ;

Frogley, Mark D. ;

Rudic, Svemir ;

Manuel, Pascal ;

Ramirez-Cuesta, Anibal J. ;

Yang, Sihai ;

Schroder, Martin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (08) :3153-3161

[7]

Kim D.W., 2020, ANGEW CHEM, V132, P22720

[8] Ammonia Capture via an Unconventional Reversible Guest-Induced Metal-Linker Bond Dynamics in a Highly Stable Metal-Organic Framework [J].

Lyu, Pengbo ;

Wright, Ashley M. ;

Lopez-Olvera, Alfredo ;

Mileo, Paulo G. M. ;

Antonio Zarate, J. ;

Martinez-Ahumada, Eva ;

Martis, Vladimir ;

Williams, Daryl R. ;

Dinca, Mircea ;

Ibarra, Ilich A. ;

Maurin, Guillaume .

CHEMISTRY OF MATERIALS, 2021, 33 (15) :6186-6192

[9] A Roadmap to the Ammonia Economy [J].

MacFarlane, Douglas R. ;

Cherepanov, Pavel V. ;

Choi, Jaecheol ;

Suryanto, Bryan H. R. ;

Hodgetts, Rebecca Y. ;

Bakker, Jacinta M. ;

Vallana, Federico M. Ferrero ;

Simonov, Alexandr N. .

JOULE, 2020, 4 (06) :1186-1205

[10] Exceptional Packing Density of Ammonia in a Dual-Functionalized Metal-Organic Framework [J].

Marsh, Christopher ;

Han, Xue ;

Li, Jiangnan ;

Lu, Zhenzhong ;

Argent, Stephen P. ;

da Silva, Ivan ;

Cheng, Yongqiang ;

Daemen, Luke L. ;

Ramirez-Cuesta, Anibal J. ;

Thompson, Stephen P. ;

Blake, Alexander J. ;

Yang, Sihai ;

Schroder, Martin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (17) :6586-6592

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