An ordered bcc CuPd nanoalloy synthesised via the thermal decomposition of Pd nanoparticles covered with a metal-organic framework under hydrogen gas

被引：28

作者：

Li, Guangqin ^{[1
]}

Kobayashi, Hirokazu ^{[1
,2
]}

Kusada, Kohei ^{[1
,2
]}

Taylor, Jared M. ^{[1
,2
]}

Kubota, Yoshiki ^{[3
]}

Kato, Kenichi ^{[4
,5
]}

Takata, Masaki ^{[4
,5
]}

Yamamoto, Tomokazu ^{[2
,6
]}

Matsumura, Syo ^{[2
,6
,7
,8
]}

Kitagawa, Hiroshi ^{[1
,2
,8
,9
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Div Chem, Sakyo Ku, Kyoto 6068502, Japan

[2] JST CREST, Chiyoda Ku, Tokyo 1020076, Japan

[3] Osaka Prefecture Univ, Grad Sch Sci, Dept Phys Sci, Sakai, Osaka 5998531, Japan

[4] RIKEN, SPring Ctr 8, Sayo, Hyogo 6795148, Japan

[5] Japan Synchrotron Radiat Res Inst, Sayo, Hyogo 6795198, Japan

[6] Kyushu Univ, Res Lab High Voltage Electron Microscope, Nishi Ku, Fukuoka 8190395, Japan

[7] Kyushu Univ, Dept Appl Quantum Phys & Nucl Engn, Nishi Ku, Fukuoka 8190395, Japan

[8] Kyushu Univ, INAMORI Frontier Res Ctr, Nishi Ku, Fukuoka 8190395, Japan

[9] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 89期

关键词：

CATALYTIC-ACTIVITY; ZNO NANOPARTICLES; NANOCRYSTALS; OXIDATION; STORAGE;

D O I：

10.1039/c4cc05941g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Presented here is the synthesis of an ordered bcc copper-palladium nanoalloy, via the decomposition of a Pd nanoparticle@metal-organic framework composite material. In situ XRD measurements were performed in order to understand the mechanism of the decomposition process. This result gives a further perspective into the synthesis of new nanomaterials via metal-organic framework decomposition.

引用

页码：13750 / 13753

页数：4

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