Synthesis, NMR spectroscopy, and conformational analysis of α-dimethylsilyl esters

被引：3

作者：

Kaimakliotis, C ^{[1
]}

Arthanari, H ^{[1
]}

Fry, AJ ^{[1
]}

机构：

[1] Wesleyan Univ, Dept Chem, Hall Atwater Lab, Middletown, CT 06459 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 671卷 / 1-2期

基金：

美国国家科学基金会;

关键词：

Si-29-NMR spectroscopy; conformational analysis; alpha-dimethylsilyl esters;

D O I：

10.1016/S0022-328X(03)00073-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The conformational properties of alpha-dimethylsilyl esters, synthesized in excellent yields by reaction of ester enolates with chlorodimethylsilane (DMSCl), have been explored by both molecular mechanics calculations and a variety of H-1- and Si-29-NMR spectroscopic experiments. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：126 / 130

页数：5

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