Synthesis and structure characterization of two cadmium coordination polymers based on μ2-bridging bidentate hydrazine ligand

被引：0

作者：

Shanthakumar, D. Santhosh ^{[1
]}

Pradeep, R. ^{[2
]}

Subramani, B. ^{[3
]}

Sivasankar, B. N. ^{[2
]}

机构：

[1] Sri Krishna Coll Technol, Dept Chem, Coimbatore 641042, Tamil Nadu, India

[2] Govt Arts Coll, Dept Chem, The Nilgiris 643002, Tamil Nadu, India

[3] Crescent Sch, Dept Chem, Madras 600048, Tamil Nadu, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2018年 / 57卷 / 07期

关键词：

Coordination polymers; Cadmium coordination polymers; Crystal structures; Hydrazines; Malonates; mu(2)-Bridging bidentate; mu(3)-Bridging pentadentate; CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURE; COMPLEXES; CATION; NICKEL(II); COBALT(II); ZINC(II);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis, single crystal structures, spectral and thermal characteristics of two cadmium coordination polymers, viz., [Cd(NO3)(2)(N2H4)(2)] (1) [Cd(C3H2O4)(N2H4)] (where C3H2O4 is malonate) (2) are reported. The N.-bridging bidentate binding mode of the crystallographically unique hydrazine ligands in (1) leads to a one-dimensional polymeric structure extending along c axis. The central Cd(II) in (2) exhibits hepta-coordination and is bonded to a unique malonate anion which exhibits a mu(3)-bridging pentadentate coordination, extending the structure along the a axis. The bridging bidentate binding of the crystallographically independent hydrazine ligand extends along b axis resulting in a 2-D structure.

引用

页码：905 / 909

页数：5

共 24 条

[1] Mono- and bis(hydrazine) complexes of osmium(II):: Synthesis, reactions, and X-ray crystal structure of the [Os(NH2NH2)2{P(OEt)3}4](BPh4)2 derivative
Albertin, G
Antoniutti, S
Bacchi, A
Bergano, M
Bordignon, E
Pelizzi, G
[J]. INORGANIC CHEMISTRY, 1998, 37 (03) : 479 - 489
[2] Aryldiazene, aryldiazenido, and hydrazine complexes of manganese. Preparation, characterization, and x-ray crystal structures of [Mn(CO)(3)(4-CH3C6H4N=NH){PPh(OEt)(2)}(2)]BF4 and [Mn(CO)(3)(NH2NH2){PPh(OEt)(2)}(2)]BPH4 derivatives
Albertin, G
Antoniutti, S
Bacchi, A
Bordignon, E
Busatto, F
Pelizzi, G
[J]. INORGANIC CHEMISTRY, 1997, 36 (07) : 1296 - 1305
[3] COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92
ALTOMARE, A
CASCARANO, G
GIACOVAZZO, C
GUAGLIARDI, A
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) : 343 - 350
[4] [Anonymous], 2004, APEX2 SAINT PLUS
[5] CRYSTAL AND MOLECULAR STRUCTURE OF BIS(HYDRAZINECARBOXYLATO-N'O)MANGANESE(2) DIHYDRATE
BRAIBANTI, A
TIRIPICCHIO, A
LANFREDI, AM
CAMELLINI, M
[J]. ACTA CRYSTALLOGRAPHICA, 1967, 23 : 248 - +
[6] NEW GROUP-2 METAL HYDRAZINECARBOXYLATES - A NOVEL COORDINATION MODE FOR HYDRAZINECARBOXYLATE IN A POLYMERIC, 10-CO-ORDINATE BARIUM COMPLEX
EDWARDS, DA
KEILY, JF
MAHON, MF
MOLLOY, KC
THOMPSETT, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (23): : 3471 - 3474
[7] Farrugia L. J., 1997, J APPL CRYSTALLOGR, V30, P565, DOI DOI 10.1107/S0021889897003117
[8] CRYSTAL STRUCTURE OF BIS(HYDRAZINE)ZINC ISOTHIOCYANATE
FERRARI, A
BRAIBANT.A
BIGLIARD.G
LANFREDI, AM
[J]. ACTA CRYSTALLOGRAPHICA, 1965, 18 : 367 - &
[9] CHAINS OF COMPLEXES IN CRYSTAL STRUCTURE OF BISHYDRAZINE ZINC CHLORIDE
FERRARI, A
BRAIBANTI, A
BIGLIARDI, G
[J]. ACTA CRYSTALLOGRAPHICA, 1963, 16 (06): : 498 - +
[10] SYNTHESIS, CHARACTERIZATION AND THERMAL-PROPERTIES OF HYDRAZINIUM METAL OXALATE HYDRATES - CRYSTAL AND MOLECULAR-STRUCTURE OF HYDRAZINIUM COPPER OXALATE MONOHYDRATE
GAJAPATHY, D
GOVINDARAJAN, S
PATIL, KC
MANOHAR, H
[J]. POLYHEDRON, 1983, 2 (09) : 865 - 873

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