NASICON structure for alkaline ion recognition

被引：18
作者：
Cretin, M [1 ]
Khireddine, H [1 ]
Fabry, P [1 ]
机构：
[1] ENSEEG, Lab Electrochim & Physicochim Mat & Interfaces, F-38402 St Martin Dheres, France
来源：
SENSORS AND ACTUATORS B-CHEMICAL | 1997年 / 43卷 / 1-3期
关键词：
ceramic membranes; ion-sensitive electrode (ISE); lithium; Na superionic conductor (NASICON); selectivity; sodium;
D O I：
10.1016/S0925-4005(97)00118-4
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Crystallized fast-alkaline conductors have promising properties for ion electrochemical sensors. Their conductivity at room temperature is very high (about 10(-4)-10(-3) S cm(-1)), The selectivity effect of such membranes is based on the calibration of conductive sites in the structure. NASICON materials are good examples from this point of view. Suitable cationic substitutions allow to adjust the size of the conduction sites and then to improve the selectivity effect. Recent experimental results on Na+ and Li+ membranes are shown in this field. (C) 1997 Elsevier Science S.A.
引用
收藏
页码：224 / 229
页数：6
相关论文
共 25 条
  • [1] IONIC-CONDUCTIVITY OF SOLID ELECTROLYTES BASED ON LITHIUM TITANIUM PHOSPHATE
    AONO, H
    SUGIMOTO, E
    SADAOKA, Y
    IMANAKA, N
    ADACHI, G
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (04) : 1023 - 1027
  • [2] A NEW DOUBLE-JET CELL FOR FAST ION-SENSITIVE ELECTRODES
    ATTARI, M
    FABRY, P
    MALLIE, H
    QUEZEL, G
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 1993, 15 (1-3) : 173 - 178
  • [3] CONDUCTIVE EPOXY-GRAPHITE COMPOSITE AS A SOLID INTERNAL REFERENCE IN A NASICON-BASED SODIUM ION-SELECTIVE ELECTRODE FOR FLOW-INJECTION ANALYSIS
    BARTROLI, J
    ALERM, L
    FABRY, P
    SIEBERT, E
    [J]. ANALYTICA CHIMICA ACTA, 1995, 308 (1-3) : 102 - 108
  • [4] RELATION STRUCTURE FAST ION CONDUCTION IN THE NASICON SOLID-SOLUTION
    BOILOT, JP
    COLLIN, G
    COLOMBAN, P
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1988, 73 (01) : 160 - 171
  • [5] PERFORMANCE-CHARACTERISTICS OF SODIUM SUPER IONIC CONDUCTOR PREPARED BY THE SOL-GEL ROUTE FOR SODIUM-ION SENSORS
    CANEIRO, A
    FABRY, P
    KHIREDDINE, H
    SIEBERT, E
    [J]. ANALYTICAL CHEMISTRY, 1991, 63 (22) : 2550 - 2557
  • [6] GEL TECHNOLOGY IN CERAMICS, GLASS-CERAMICS AND CERAMIC CERAMIC COMPOSITES
    COLOMBAN, P
    [J]. CERAMICS INTERNATIONAL, 1989, 15 (01) : 23 - 50
  • [7] STUDY OF LI1+XALXTI2-X(PO4)(3) FOR LI+ POTENTIOMETRIC SENSORS
    CRETIN, M
    FABRY, P
    ABELLO, L
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1995, 15 (11) : 1149 - 1156
  • [8] CRETIN M, 1996, THESIS INPG GRENOBLE
  • [9] IONIC EXCHANGE AND SELECTIVITY OF NASICON SENSITIVE MEMBRANES
    DAMASCENO, O
    SIEBERT, E
    KHIREDDINE, H
    FABRY, P
    [J]. SENSORS AND ACTUATORS B-CHEMICAL, 1992, 8 (03) : 245 - 248
  • [10] FABRICATION OF NASICON ELECTROLYTES FROM METAL ALKOXIDE DERIVED GELS
    ENGELL, J
    MORTENSEN, S
    MOLLER, L
    [J]. SOLID STATE IONICS, 1983, 9-10 (DEC) : 877 - 884
123