Palladium/norbornene chemistry: an unexpected route to methanocarbazole derivatives via three Csp3-Csp2/Csp3-N/Csp2-N bond formations in a single synthetic sequence

被引：29

作者：

Jafarpour, Farnaz ^{[1
]}

Jalalimanesh, Nafiseh ^{[1
]}

Teimouri, Mahdieh ^{[1
]}

Shamsianpour, Mitra ^{[1
]}

机构：

[1] Univ Tehran, Coll Sci, Sch Chem, Tehran, Iran

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 01期

关键词：

TETRASUBSTITUTED HELICAL ALKENES; PALLADIUM-CATALYZED SYNTHESIS; ONE-STEP SYNTHESIS; C-H AMINATION; ARYL IODIDES; DIRECT ARYLATION; EXPEDITIOUS SYNTHESIS; SOLAR-CELLS; O-TERARYLS; FUNCTIONALIZATION;

D O I：

10.1039/c4cc06789d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Catellani reaction terminated by palladacycle amination leading to methanocarbazoles is reported. The outcome is the formation of three different Csp(3)-Csp(2)/Csp(3)-N/Csp(2)-N bonds through a Heck reaction/C-H activation/double amination cascade in one process.

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页码：225 / 228

页数：4

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