Photoluminescence Properties of SrMoO4:Eu3+, Sm3+ Nanophosphors Prepared by Sol-Gel Method

被引:6
作者
Xu, Xiaoli [1 ]
Dong, Wenge [1 ]
Ding, Jiajun [1 ]
Feng, Yuanzhang [1 ]
Zhang, Fang [1 ]
Ma, Lingli [1 ]
Peng, Zifei [1 ]
机构
[1] Shanghai Normal Univ, Dept Chem, Shanghai 200234, Peoples R China
关键词
SrMoO4; Doping; Nanophosphors; Sol-Gel Method; Rare Earth; Photoluminescence; CHARGE COMPENSATION; ENERGY-TRANSFER; PHOSPHOR; LUMINESCENCE; EU3+;
D O I
10.1166/jnn.2015.10024
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel red light-emitting nanophosphors of SrMoO4:Eu3+, Sm3+ were synthesized by a facile sol gel method. Particles have sizes in the range of 50-80 nm. The structures, morphologies and optical properties of as-prepared products were characterized by means of X-ray diffraction (XRD), transmission electron microscope (TEM) and photo luminescent (PL). The results indicate that the red emission intensity was enhanced significantly with the increase of Sm3+ doping concentrations. When the mole fraction of Sm3+ is 2%, the emission intensity of red light is the strongest. It has been found that the incorporation of R+(Li+, Na+) into SrMoO4:Eu3+, Sm3+ phosphor could lead to a remarkable increase of photoluminescence. Thus, it is considered to be efficient red-emitting phosphors.
引用
收藏
页码:5434 / 5437
页数:4
相关论文
共 22 条
[2]   Sol-gel synthesis of red-phosphors [NaxGd1-x/3-zEuz]MoyW1-yO4 powers and luminescence properties [J].
Cao, Fa-Bin ;
Li, Liao-Sha ;
Tian, Yan-Wen ;
Gao, Zhi-Fang ;
Chen, Yong-Jie ;
Xiao, Lin-Jiu ;
Wu, Xing-Rong .
OPTICAL MATERIALS, 2011, 33 (06) :751-754
[3]   Upconversion luminescence of Eu3+ and Mn2+ in ZnS:Mn2+, Eu3+ codoped nanoparticles [J].
Chen, W ;
Joly, AG ;
Malm, JO ;
Bovin, JO .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (02) :667-672
[4]   Luminescence enhancement of EuS nanoclusters in zeolite [J].
Chen, W ;
Zhang, XH ;
Huang, YN .
APPLIED PHYSICS LETTERS, 2000, 76 (17) :2328-2330
[5]  
Chiu C., 2008, J ELECTROCHEM SOC, V71, P155
[6]  
Hu Y., 2005, J ALLOY COMPD, V2, P390
[7]   Dynamical processes of energy transfer in red emitting phosphor CaMoOw4:Sm3+, Eu3+ [J].
Jin, Ye ;
Hao, Zhendong ;
Zhang, Xia ;
Luo, Yongshi ;
Wang, Xiaojun ;
Zhang, Jiahua .
OPTICAL MATERIALS, 2011, 33 (11) :1591-1594
[8]   Radiation damage of PbWO4 crystals due to irradiation by 60Co gamma rays [J].
Kozma, P ;
Bajgar, R ;
Kozma, P .
RADIATION PHYSICS AND CHEMISTRY, 2002, 65 (02) :127-130
[9]   Preparation and luminescence properties of CaSnO3:SM3+ phosphor emitting in the reddish orange region [J].
Lei, Bingfu ;
Li, Bin ;
Zhang, Haoran ;
Li, Wenlian .
OPTICAL MATERIALS, 2007, 29 (11) :1491-1494
[10]   Improved optical photoluminescence by charge compensation in the phosphor system CaMoO4:: Eu3+ [J].
Liu, Jie ;
Lian, Hongzhou ;
Shi, Chunshan .
OPTICAL MATERIALS, 2007, 29 (12) :1591-1594