Selective reduction of carboxylic acids to aldehydes with hydrosilane via photoredox catalysis

被引：33

作者：

Zhang, Muliang ^{[1
]}

Li, Nan ^{[1
]}

Tao, Xingyu ^{[1
]}

Ruzi, Rehanguli ^{[1
]}

Yu, Shouyun ^{[1
]}

Zhu, Chengjian ^{[1
,2
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Jiangsu Key Lab Adv Organ Mat, Nanjing 210093, Jiangsu, Peoples R China

[2] Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 73期

基金：

中国国家自然科学基金;

关键词：

REPRESENTATIVE FUNCTIONAL-GROUPS; ALPHA-KETO ACIDS; DECARBOXYLATIVE ALKYNYLATION; CHEMOSELECTIVE CONVERSION; CORRESPONDING ALDEHYDES; MERGING PHOTOREDOX; HYDRIDE REDUCTIONS; ORGANIC-COMPOUNDS; DIMETHYL SULFIDE; FACILE REDUCTION;

D O I：

10.1039/c7cc05570f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The direct reduction of carboxylic acids to aldehydes with hydrosilane was achieved through visible light photoredox catalysis. The combination of both single electron transfer and hydrogen atom transfer steps offers a novel and convenient approach to selective reduction of carboxylic acids to aldehydes. The method also features mild conditions, high yields, broad substrate scope, and good functional group tolerance, such as alkyne, ester, ketone, amide and amine groups.

引用

页码：10228 / 10231

页数：4

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