Synthesis and characterization of poly[acrylamide-co-(sodium 4-styrenesulfonate)] via inverse microemulsion polymerization

被引：5
|
作者：
Qiu, Jianhua [1 ]
Zhang, Yanwu [1 ]
Meng, Xiaohong [1 ]
Zhang, Haoqin [1 ]
Liu, Jindun [1 ]
机构：
[1] Zhengzhou Univ, Sch Chem Engn, Zhengzhou 450001, Henan, Peoples R China
来源：
POLYMER INTERNATIONAL | 2010年 / 59卷 / 01期
基金：
中国国家自然科学基金;
关键词：
acrylamide; sodium; 4-styrenesulfonate; inverse microemulsion; reactivity ratios; MOSAIC COMPOSITE MEMBRANES; MODIFIED POLYACRYLAMIDES; ANIONIC POLYACRYLAMIDE; REACTIVITY RATIOS; AQUEOUS-SOLUTION; CHAIN TRANSFER; ACRYLAMIDE; COPOLYMERIZATION; DISPERSIONS; PARTICLES;
D O I：
10.1002/pi.2692
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An anionic polyelectrolyte based on acrylamide (Am) and sodium 4-styrenesulfonate (SSS) was synthesized via the inverse microemulsion polymerization technique. The hydrophilic - lipophilic balance (HLB) values of the surfactant and the composition of the inverse microemulsion system were determined using pseudoternary phase diagrams. The reactivity ratios of Am and SSS in inverse microemulsion polymerization were calculated using the Kelen-Tudos method. The optimum HLB value of the surfactant for the inverse microemulsion system was 8.58. The composition of the inverse microemulsion system was surfactants (25 wt%), cyclohexane (59 wt%) and aqueous solution of monomers (16 wt%). Am (r(1)) and SSS (r(2)) reactivity ratios were 0.61 and 1.99, respectively. Monomer reactivity ratios of Am and SSS determined in the present study differ from those reported for solution radical copolymerization. This indicates that the difference in microenvironment in solution and microemulsion plays an important role in governing the reactivity ratios of the monomers. (C) 2009 Society of Chemical Industry
引用
收藏
页码：78 / 84
页数：7
相关论文
共 50 条
  • [21] Preparation and Absorbencies of Poly(acrylate-co- acrylamide) Superabsorbent by Inverse Suspension Polymerization
    Xie, Jian-jun
    Zhang, Huiying
    Zeng, Nian
    Ran, De-long
    FUNDAMENTAL OF CHEMICAL ENGINEERING, PTS 1-3, 2011, 233-235 : 1257 - 1261
  • [22] Wrapping carbon nanotubes with poly (sodium 4-styrenesulfonate) for enhanced adsorption of methylene blue and its mechanism
    Zhang, Zhao-yang
    Xu, Xue-cheng
    CHEMICAL ENGINEERING JOURNAL, 2014, 256 : 85 - 92
  • [23] Poly(sodium 4-styrenesulfonate) modified carbon nanoparticles by a thermo-mechanical technique and its reinforcement in natural rubber latex
    He, Xuelian
    Peng, Zheng
    Yu, Na
    Han, Jingjie
    Wu, Chifei
    COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (14) : 3027 - 3032
  • [24] Development of novel cellulose acetate-g-poly (sodium 4-styrenesulfonate) proton conducting polyelectrolyte polymer
    Shalaby, Asmaa Attya
    Abd Elmageed, Mohamed Hussien
    Malash, Gihan Farouk
    Tamer, Tamer Mahmoud
    Omer, Ahmed Mohamed
    Mohy-Eldin, Mohamed Samir
    Khalifa, Randa Eslah
    JOURNAL OF SAUDI CHEMICAL SOCIETY, 2021, 25 (10)
  • [25] Synthesis and characterization of nano-sized poly[(butyl acrylate)-co-(methyl methacrylate)-co-(methacrylic acid)] latex via differential microemulsion polymerization
    Taenghom, Temsook
    Pan, Qinmin
    Rempel, Garry L.
    Kiatkamjornwong, Suda
    COLLOID AND POLYMER SCIENCE, 2013, 291 (06) : 1365 - 1374
  • [26] Preparation of polyaniline coated polystyrene-poly(styrene-co-sodium 4-styrenesulfonate) microparticles and the further fabrication of hollow polyaniline microspheres
    Sun, Libo
    Shi, Yuanchang
    Chu, Linya
    Xu, Xiaokuai
    Liu, Jiurong
    JOURNAL OF APPLIED POLYMER SCIENCE, 2012, 126 (03) : 870 - 876
  • [27] Synthesis of poly(methyl methacrylate) nanoparticles via differential microemulsion polymerization
    Yuan, Liang
    Wang, Yun
    Pan, Maozhi
    Rempel, Garry L.
    Pan, Qinmin
    EUROPEAN POLYMER JOURNAL, 2013, 49 (01) : 41 - 48
  • [28] Synthesis of poly(acrylamide-co-divinylbenzene) microspheres by precipitation polymerization
    Jin, JM
    Yang, SY
    Shim, SE
    Choe, SJ
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (21) : 5343 - 5346
  • [29] Synthesis and Water Absorbency Property of Monodispersed Poly (acrylamide-co-itaconic acid) Spheres by Dispersion Polymerization
    Shi, Dongjian
    Gao, Yan
    Sun, Qiwei
    Chen, Mingqing
    INTEGRATED FERROELECTRICS, 2014, 153 (01) : 23 - 32
  • [30] Synthesis of poly(vinyl pyrrolidon-co-acrylamide) flocculants by radical polymerization
    Cakmak, I
    Tuter, M
    ASIAN JOURNAL OF CHEMISTRY, 2004, 16 (3-4) : 1703 - 1706
12345