Synthesis, structures and luminescent properties of two zinc (II) complexes from flexible bis(tetrazolate) ligands

被引：6
作者：
Li, Xiaoju [1 ,2 ]
Li, Zhifa [1 ,2 ]
Xu, Xiahong [1 ,2 ]
Guo, Xiaofang [1 ,2 ]
机构：
[1] Fujian Normal Univ, Fujian Key Lab Polymer Mat, Coll Chem & Chem Engn, Fuzhou, Peoples R China
[2] Fujian Normal Univ, Coll Mat Sci & Engn, Fuzhou, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 68卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Coordination polymer; Crystal structure; Zinc(II); Fluorescence; Tetrazolate; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; ENERGETIC SALTS; ARCHITECTURES; CADMIUM(II); BIS(IMIDAZOLYL); CONSTRUCTION; TETRAZOLATE; NETWORKS;
D O I：
10.1080/00958972.2014.983914
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two Zn(II) coordination polymers, [Zn2H(dte)(2)(HCOO)(H2O)(CH3OH)](n) (1) and [Zn-2(dtp)(OH)(2)](n) (2), with flexible 1,2-di(1H-tetrazol-5-yl)ethane (H(2)dte) and 1,2-di(1H-tetrazol-5-yl)propane (H(2)dtp) have been prepared. The dte(2-) and dtp(2-) ligands adopt chelating and bridging coordination, and link three Zn(II) ions into a 2-D layer and a 1-D chain, respectively. The anionic formate and hydroxyl bridges are formed in situ, which further extend the 2-D layer and the 1-D chain into 3-D and 2-D networks, respectively. Complexes 1 and 2 showed a maximum fluorescent emission at 403 and 422nm, respectively.
引用
收藏
页码：195 / 205
页数：11
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