Synthesis of Aromatic Macrocyclic Amphiphiles and their Self-Assembling Behavior in Aqueous Solution

被引：3
作者：
Kim, Jung-Keun [1 ,2 ]
Lee, Eunji [1 ,2 ]
Lee, Myongsoo [1 ,2 ]
机构：
[1] Seoul Natl Univ, Ctr Supramol Nanoassembly, Seoul 151747, South Korea
[2] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2010年 / 31卷 / 11期
关键词：
amphiphiles; macrocycles; self-assembly; supramolecular structures; vesicles; SHAPE-PERSISTENT; VESICLES; MICELLES; ARCHITECTURES; ASSOCIATION; MATTER;
D O I：
10.1002/marc.200900879
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A triblock amphiphilic macrocycle consisting of a macrocyclic aromatic segment, a hydrophilic oligo(ethylene oxide) branch, and a hydrophobic alkyl dendron is successfully synthesized and characterized. The resulting cyclic amphiphile is observed to self-assemble into hollow double-layered capsules in aqueous solution, as confirmed by dynamic light scattering and cryogenic transmission electron microscopy investigations. The capsules are able to encapsulate hydrophobic guest molecules through aromatic interactions with high stability.
引用
收藏
页码：980 / 985
页数：6
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