Comparison of predictions of microsegregation in the Ni-Cr-Mo system to experimental measurements

被引：8
作者：
Cefalu, Shawn A. [1 ]
Krane, Matthew J. M. [1 ]
机构：
[1] Purdue Univ, Sch Mat Engn, W Lafayette, IN 47907 USA
来源：
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2007年 / 454卷
关键词：
microsegregation; solute distributions; Ni-Cr-Mo alloy; multicomponent solidification;
D O I：
10.1016/j.msea.2006.11.060
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Experimental measurements of microsegregation in six Ni-Cr-Mo alloys are compared to closed system simulations. The calculations accurately predict the segregation of molybdenum, but underpredict the primary solid fraction and tend to overpredict chromium segregation at late stages of solidification. Analysis of the data suggests that the difference between the calculations and the measurements may be caused by a delay in the nucleation of the secondary phases. Upon adjusting for this delay and using the experimentally determined partition coefficients, the model better predicts the phase fractions and segregation in the alloys. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：371 / 378
页数：8
相关论文
共 23 条
  • [11] Solidification of ternary metal alloys .1. Model development
    Krane, MJM
    Incropera, FP
    Gaskell, DR
    [J]. INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER, 1997, 40 (16) : 3827 - 3835
  • [12] KURZ W, 1992, FUNDAMENTALS SOLIDIF, P122
  • [13] Kurzydlowski K.J., 1995, Quantitative Description of the Microstructure of Materials
  • [14] A VOLUME-AVERAGED 2-PHASE MODEL FOR TRANSPORT PHENOMENA DURING SOLIDIFICATION
    NI, J
    BECKERMANN, C
    [J]. METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY, 1991, 22 (03): : 349 - 361
  • [15] DETERMINATION OF ISOTHERMAL SECTIONS OF NICKEL RICH PORTION OF NI-CR-MO SYSTEM BY ANALYTICAL ELECTRON-MICROSCOPY
    RAGHAVAN, M
    MUELLER, RR
    VAUGHN, GA
    FLOREEN, S
    [J]. METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1984, 15 (05): : 783 - 792
  • [16] MODELING OF MICRO-MACROSEGREGATION IN SOLIDIFICATION PROCESSES
    RAPPAZ, M
    VOLLER, V
    [J]. METALLURGICAL TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1990, 21 (03): : 749 - 753
  • [17] SUNDARRAJ S, 1992, MICRO MACRO SCALE PH, P35
  • [18] SUNDQUIST BE, 1961, T METALL SOC AIME, V221, P157
  • [19] THOMAS BG, 1995, MAT PROCESSING COMPU, V2, P3
  • [20] Voller VR, 2001, COMPUTATIONAL MODELING OF MATERIALS, MINERALS AND METALS PROCESSING, P41
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