Comparison of predictions of microsegregation in the Ni-Cr-Mo system to experimental measurements

被引:8
作者
Cefalu, Shawn A. [1 ]
Krane, Matthew J. M. [1 ]
机构
[1] Purdue Univ, Sch Mat Engn, W Lafayette, IN 47907 USA
来源
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING | 2007年 / 454卷
关键词
microsegregation; solute distributions; Ni-Cr-Mo alloy; multicomponent solidification;
D O I
10.1016/j.msea.2006.11.060
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Experimental measurements of microsegregation in six Ni-Cr-Mo alloys are compared to closed system simulations. The calculations accurately predict the segregation of molybdenum, but underpredict the primary solid fraction and tend to overpredict chromium segregation at late stages of solidification. Analysis of the data suggests that the difference between the calculations and the measurements may be caused by a delay in the nucleation of the secondary phases. Upon adjusting for this delay and using the experimentally determined partition coefficients, the model better predicts the phase fractions and segregation in the alloys. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:371 / 378
页数:8
相关论文
共 23 条
  • [1] TRACER DIFFUSION IN CHROMIUM-NICKEL SYSTEM
    ASKILL, J
    [J]. PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1971, 8 (02): : 587 - &
  • [2] BLOOM DS, 1954, T AIME, V198, P261
  • [3] Microsegregation in open and closed multicomponent systems
    Cefalu, SA
    Krane, MJM
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2003, 359 (1-2): : 91 - 99
  • [4] CEFALU SA, 2001, THESIS PURDUE U W LA
  • [5] Modeling of microsegregation in macrosegregation computations
    Combeau, H
    Drezet, JM
    Mo, A
    Rappaz, M
    [J]. METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1996, 27 (08): : 2314 - 2327
  • [6] Modelling of microsegregation
    Doré, X
    Rappaz, M
    [J]. SOLIDIFICATION AND GRAVITY 2000, 2000, 329-3 : 331 - 337
  • [7] A technique for characterizing microsegregation in multicomponent alloys and its application to single-crystal superalloy castings
    Ganesan, M
    Dye, D
    Lee, PD
    [J]. METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2005, 36A (08): : 2191 - 2204
  • [8] HEIJWEGEN CP, 1974, ACTA METALL MATER, V22, P1269, DOI 10.1016/0001-6160(74)90140-0
  • [9] HOLLOMON JH, 1951, T AM I MIN MET ENG, V191, P803
  • [10] Predictors microstructure and microsegregation multicomponent alloys
    Kraft, T
    Chang, YA
    [J]. JOM-JOURNAL OF THE MINERALS METALS & MATERIALS SOCIETY, 1997, 49 (12): : 20 - 28