Solvothermal in situ synthesis of (Schiff-base)-containing dinuclear cobalt compound

被引：8
作者：
Luo, Feng [1 ]
Luo, Ming-biao [1 ]
机构：
[1] E China Inst Technol, Coll Biol Chem & Mat Sci, Fuzhou 344000, Jiangxi, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 02期
关键词：
Solvothermal synthesis; Schiff base; Dinuclear cobalt compound; Antiferromagnetic interaction; SCHIFF-BASE COMPLEXES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; B-12; MODELS; COORDINATION; CLUSTERS; CATIONS; LIGAND; IONS;
D O I：
10.1016/j.inoche.2009.12.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new dinuclear cobalt compound, namely Co(2)(L)(H(2)O)Cl(2) (1, H(2)L = N,N'-o-phenylenebis(salicylide-neimine) was obtained by one-pot solvothermal self-assembly of CoCl(2), 1,2-phenylenediamine, and salicylaldehyde in C(2)H(5)OH. The magnetic studies suggest weak antiferromagnetic behavior and the magnetic data were interpreted by means of a dinuclear cobalt model with the parameters of g = 2.12, J = -1.25 cm(-1), theta = -3.12 K. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：319 / 321
页数：3
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