Solvothermal in situ synthesis of (Schiff-base)-containing dinuclear cobalt compound

被引：8

作者：

Luo, Feng ^{[1
]}

Luo, Ming-biao ^{[1
]}

机构：

[1] E China Inst Technol, Coll Biol Chem & Mat Sci, Fuzhou 344000, Jiangxi, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 02期

关键词：

Solvothermal synthesis; Schiff base; Dinuclear cobalt compound; Antiferromagnetic interaction; SCHIFF-BASE COMPLEXES; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; B-12; MODELS; COORDINATION; CLUSTERS; CATIONS; LIGAND; IONS;

D O I：

10.1016/j.inoche.2009.12.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dinuclear cobalt compound, namely Co(2)(L)(H(2)O)Cl(2) (1, H(2)L = N,N'-o-phenylenebis(salicylide-neimine) was obtained by one-pot solvothermal self-assembly of CoCl(2), 1,2-phenylenediamine, and salicylaldehyde in C(2)H(5)OH. The magnetic studies suggest weak antiferromagnetic behavior and the magnetic data were interpreted by means of a dinuclear cobalt model with the parameters of g = 2.12, J = -1.25 cm(-1), theta = -3.12 K. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：319 / 321

页数：3

共 23 条

[1] Multinuclear Cd2, Cd3 and 1-D framework structures of Cd(II) Schiff base complexes [J].

Agapiou, Kyriacos ;

Mejia, Michelle L. ;

Yang, Xiaoping ;

Holliday, Bradley J. .

DALTON TRANSACTIONS, 2009, (21) :4154-4159

[2] Copper(I/II) and cobalt(II) coordination chemistry of relevance to controlled radical polymerization processes [J].

Baisch, Ulrich ;

Poli, Rinaldo .

POLYHEDRON, 2008, 27 (9-10) :2175-2185

[3] STRUCTURAL ASPECTS OF METAL-COMPLEXES WITH SOME TETRADENTATE SCHIFF-BASES [J].

CALLIGARIS, M ;

RANDACCIO, L ;

NARDIN, G .

COORDINATION CHEMISTRY REVIEWS, 1972, 7 (04) :385-+

[4] STERIC STRAIN IN COBALT(III) COMPOUNDS - CRYSTAL AND MOLECULAR-STRUCTURE OF DIBENZOYLMETHANATO-O,O'-[NN'-O-PHENYLENEBIS(SALICYLIDENEIMINATO)]-COBALT(III) [J].

CUMMINS, D ;

MCKENZIE, ED ;

MILBURN, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (02) :130-135

[5]

da Silva J.J.R. Frausto., 1997, The Biological Chemistry of the Elements

[6] ADDITION OF TRANSITION-METAL DIHALIDES TO ACETYLACETONATES OF DIVALENT METAL-IONS [J].

DORING, M ;

GORLS, H ;

UHLIG, E ;

BRODERSEN, K ;

DAHLENBURG, L ;

WOLSKI, A .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1992, 614 (08) :65-72

[7] REACTION OF ELEMENTAL SULFUR WITH COBALT(II)-SCHIFF-BASE COMPLEXES - SYNTHESIS OF MU-DISULPHIDO AND MU-TETRASULPHIDO BINUCLEAR COBALT(III) COMPLEXES - CRYSTAL-STRUCTURES OF 2 BINUCLEAR COBALT(III)-SCHIFF-BASE COMPLEXES [J].

FLORIANI, C ;

FIALLO, M ;

CHIESIVILLA, A ;

GUASTINI, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (06) :1367-1376

[8] ALKALI-METAL CATIONS CONTROLLING THE REACTIVITY OF COBALT(II) SCHIFF-BASE COMPLEXES - SYNTHESIS OF A MU-PERSULFIDO-LIGAND FROM S-8 REACTING WITH A COBALT(II) OXYGEN CARRIER COMPOUND [J].

GAMBAROTTA, S ;

FIALLO, ML ;

FLORIANI, C ;

CHIESIVILLA, A ;

GUASTINI, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (09) :503-505

[9]

KAHN O, 1993, MOL MAGNET

[10] CATALYTIC ASYMMETRIC OXIDATIONS USING OPTICALLY-ACTIVE (SALEN)MANGANESE(III) COMPLEXES AS CATALYSTS [J].

KATSUKI, T .

COORDINATION CHEMISTRY REVIEWS, 1995, 140 :189-214

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