A hemicyanine-based near-infrared fluorescent probe for vapor-phase hydrazine detection and bioimaging in a complete aqueous media

被引：17
作者：
Wang, Yang [1 ,2 ]
Xue, Xiao-Lei [1 ]
Zhang, Qi [1 ]
Wang, Kun-Peng [1 ]
Chen, Shaojin [1 ]
Tang, Linsheng [2 ]
Hu, Zhi-Qiang [1 ]
机构：
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Life Sci, MOE, Qingdao 266042, Peoples R China
[2] Qingdao Univ Sci & Technol, Coll Chem Engn, Qingdao 266042, Peoples R China
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2022年 / 279卷
关键词：
Fluorescent probe; Hydrazine; Hemicyanine; Near-infrared fluorescence; Bioimaging; SELECTIVE DETECTION; RATIOMETRIC DETECTION; GAS STATE; EMISSION; SENSOR; RED; DEPROTECTION; CHEMOSENSOR; HYDRALAZINE; OXIDATION;
D O I：
10.1016/j.saa.2022.121406
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
A novel near-infrared fluorescent probe CyOE based on hemicyanine dye containing acetyl as a recognition site is reported. The probe CyOE shows high selectivity and sensitivity (LOD = 82 nM, 2.58 ppb), as well as good water solubility and quantitative detectability of hydrazine in the concentration range of 0-75 mu M (R-2 = 0.993). Moreover, CyOE has a significant increase in fluorescence at 735 nm with the addition of N2H4, which provides a rapid, colorimetric and gas-phase detection method for N2H4 in both aqueous solution and real water samples. In addition, CyOE is successfully utilized to visualize hydrazine in cells with low cytotoxicity and high cell permeability. (C) 2022 Elsevier B.V. All rights reserved.
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页数：9
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