Deep desulfurization of fuels: Are deep eutectic solvents the alternative for ionic liquids?

被引：39
作者：
Lima, Filipa [1 ,2 ,3 ,4 ,5 ,6 ]
Branco, Luis C. [3 ,4 ]
Silvestre, Armando J. D. [5 ,6 ]
Marrucho, Isabel M. [1 ,2 ]
机构：
[1] Univ Lisbon, Ctr Quim Estrutural, Inst Super Tecn, Ave Rovisco Pais, P-1049001 Lisbon, Portugal
[2] Univ Lisbon, Dept Engn Quim, Inst Super Tecn, Ave Rovisco Pais, P-1049001 Lisbon, Portugal
[3] Solchemar Lda, Rua 5 Outubro 121C,1 E, P-7580128 Alcacer Do Sal, Portugal
[4] Univ Nova Lisboa, Fac Ciencias & Tecnol, LAQV REQUIMTE, Campus Caparica, P-2829516 Caparica, Portugal
[5] Univ Aveiro, CICECO Aveiro Inst Mat, P-3810193 Aveiro, Portugal
[6] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal
来源：
FUEL | 2021年 / 293卷
关键词：
Deep desulfurization; Deep eutectic solvents; Ionic liquids; Extractive desulfurization; Oxidative desulfurization; Real fuel matrices; CATALYTIC OXIDATIVE DESULFURIZATION; EFFECTIVE EXTRACTIVE DESULFURIZATION; SCIENCE-AND-TECHNOLOGY; CHOLINE CHLORIDE; DIESEL FUEL; HYDRODESULFURIZATION CATALYSTS; SULFUR REMOVAL; FCC GASOLINE; THIOPHENE; DIBENZOTHIOPHENE;
D O I：
10.1016/j.fuel.2021.120297
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
The impact of fossil fuels impurities on outdoor air pollution is today a matter of great concern, with the transportation sector playing a major role. Given global efforts to reduce sulfur oxides emissions, and the increasingly tighter legislations, removal of sulfur contaminants liquid highway fuels is a pressing issue worldwide. The purpose of this review is to provide a detailed state of the art review concerning the use of deep eutectic solvents (DES) in the removal of sulfur pollutants from transportation fuels. Furthermore, a comparative evaluation regarding the use of these solvents versus Ionic Liquids (ILs) is also provided, taking into account several aspects, such as, evolution of technologies, solvents composition, extraction efficiencies and environmental and economic considerations. The large gap in terms of efficiency of the reported technologies, either using ILs or DES, between simulated matrices and real fuels is also discussed, highlighting the importance of academia and industry hand in hand work.
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页数：19
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