Investigation of copper halide:: Hydrothermal syntheses and characterization of CuBr2(C12H8N2) and Cu3Br3(C12H8N2)2

被引：0

作者：

Zhao, XL

Xu, JQ ^{[1
]}

Zhang, LJ

Yu, JH

Zeng, QX

Cui, XB

Wang, TG

Wang, TW

机构：

[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2003年 / 21卷 / 03期

关键词：

copper halide; crystal structure; hydrothermal synthesis;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of CuBr2 with 1, 10-phen-H2O (1, 10-phen = 1, 10-phenanthroline) gave two compounds: CuBr2(C12H8N2) Cu3Br3(C12H8N2)(2). Their Structures have been characterized by single-crystal X-ray diffraction analysis, elemental analyses, thermogravimetric analyses (TGA) and measurement of variable tem. perature magnetic susceptibility. Crystal data for CuBr2 (C-12-H8N2): monodinic, space group P2(1) / n, a = 0.9977(3) nm, b = 0.65138(14) mn, c = 1.8207 (4) mn, beta = 91.624 (18)degrees, V = 1.1828(5) mm(3), Z = 2. Crystal data for Cu3Br3 (C12H8N2)(2): monoclinic, space group C2/c, a = 1.00167(11) nm, b = 1.4523(4) run, c = 1.6295(3) nm, P = 94-386(14)degrees, V = 2.3635(8) mm(3), Z = 3.

引用

页码：296 / 300

页数：5

共 25 条

[1]

BLAKE AJ, 1997, UNPUB CHEM COMMUN, P1005

[2] VAN DER WAALS VOLUMES + RADII [J].