Hydrothermal synthesis of nitrogen-doped carbon dots as a sensitive fluorescent probe for the rapid, selective determination of Hg2+

被引:13
|
作者
Zhang, Yong [1 ]
Jing, Na [1 ]
Zhang, Junqiu [1 ]
Wang, Yingte [1 ]
机构
[1] Shanxi Univ, Sch Chem & Chem Engn, Taiyuan, Shanxi, Peoples R China
关键词
Hydrothermal synthesis; nitrogen-doped carbon dots; ammonium citrate; urea; Hg2+; GRAPHENE QUANTUM DOTS; TURN-ON DETECTION; GREEN SYNTHESIS; MERCURY(II) IONS; NANOPARTICLES; NANODOTS; ELECTRODES; SPECIATION; ROUTE; CELLS;
D O I
10.1080/03067319.2017.1355969
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In the present work, a green synthetic method for producing nitrogen-doped carbon dots (NCDs) by using ammonium citrate and urea is introduced. The obtained NCDs were characterised by transmission electron microscopy, Fourier transform infrared spectra, UV-vis absorption and fluorescence spectra. The results showed that the prepared NCDs were spherical with a size of about 3.5 nm, emitting strong and stable blue fluorescence when excited at 352 nm. It was noting that the NCDs enable sensitive and selective determination of Hg2+ in tap water with a linear range of 0.01-5 mg L-1 based on a possible charge transfer process. The detection limit was 9.4 mu g L-1.
引用
收藏
页码:841 / 853
页数:13
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