Synthesis and Characterization of Heterocyclic Metallomesogen

被引：0
作者：
Krishna, R. Aswini [1 ]
Boopathi, T. S. [1 ]
Senthil, S. [2 ]
机构：
[1] Amrita Vishwa Vidyapeetham, Amrita Sch Engn, Dept Sci, Coimbatore 641112, Tamil Nadu, India
[2] Govt Arts Coll, Dept Chem, Salem 7, India
来源：
MATERIALS TODAY-PROCEEDINGS | 2019年 / 18卷
关键词：
1,2,3]-triazole; metallomesogen; liquid crystal; nematic; schiff base; Ni (II) complex; smectic; SCHIFF-BASES; CU(II) COMPLEXES; LIGANDS;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The heterocyclic metallomesogen was derived from nickel (II) complexand Schiff base ligand. The target compound and its ligand were characterized by elemental analysis, FTIR, (HNMR)-H-1, (CNMR)-C-13 spectroscopy and UV-Vis spectroscopy. The spectral details were in accordance with the structure. The low value of molar conductance revealed the non-electrolytic nature of metallomesogen. The cyclic voltammetric studies explained the oxidation state of Ni(III) to Ni(II). Polarized microscopic investigation revealed the presence of Nematic and Smectic texture. Further investigation with DSC measurements confirmed the mesophase formation. It was observed that the difference in clearing temperatureand suppression of mesophaseof complex when compared to ligand was due to lack of flexibility in complex. (C) 2019 Elsevier Ltd. All rights reserved.
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页码：1670 / 1677
页数：8
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