Mineralization of reactive Black 5 in aqueous solution by ozone/H2O2 in the presence of a magnetic catalyst

被引:41
作者
Chen, Hua-Wei [2 ]
Kuo, Yu-Lin [3 ]
Chiou, Chyow-San [1 ]
You, Shih-Wei [1 ]
Ma, Chih-Ming [2 ]
Chang, Chang-Tang [1 ]
机构
[1] Natl Ilan Univ, Dept Environm Engn, Ilan 260, Taiwan
[2] St Marys Med Nursing & Management Coll, Dept Cosmet Applicat & Management, Ilan, Taiwan
[3] Natl Taiwan Univ Sci & Technol, Dept Mech Engn, Taipei, Taiwan
关键词
Mineralization; Magnetic catalyst; H2O2/O-3; Reactive Black 5; OZONATION; DEGRADATION; DECOMPOSITION; ACID; DYES;
D O I
10.1016/j.jhazmat.2009.09.122
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Particles are often too small to be separated from a reaction system and recycled, especially in wastewater treatment via a catalytic ozonation process. Thus, the objective of this study was to prepare a magnetic catalyst (SiO2/Fe3O4) that can be recycled by using an external magnetic field. The effects of the characteristics of the magnetic catalyst, pH values, catalyst dosage, and initial concentration of Reactive Black 5 (RB5) on mineralization efficiency of the magnetic catalyst/H2O2/O-3 process were also investigated. The mineralization efficiency of RB5 under various conditions followed the sequence: SiO2/Fe3O4/H2O2/O-3 > SiO2/Fe3O4/O-3 > Fe3O4/O-3 approximate to H2O2/O-3 > O-3 > SiO2/Fe3O4/H2O2. Given the results of our reuse and recovery experiments, the magnetic catalyst shows considerable promise for use in water treatment. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:795 / 800
页数:6
相关论文
共 22 条
[1]   Photochemical and heterogeneous photocatalytic degradation of waste vinylsulphone dyes: a case study with hydrolysed Reactive Black 5 [J].
Alaton, IA ;
Balcioglu, IA .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2001, 141 (2-3) :247-254
[2]   Catalytic ozonation of oxalic acid in an aqueous TiO2 slurry reactor [J].
Beltrán, FJ ;
Rivas, FJ ;
Montero-de-Espinosa, R .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 39 (03) :221-231
[3]   Degradation of the herbicide 2,4-DP by catalyzed ozonation using the O3/Fe2+/UVA system [J].
Brillas, E ;
Cabot, PL ;
Rodríguez, RA ;
Arias, C ;
Garrido, JA ;
Oliver, R .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 51 (02) :117-127
[4]  
Gottschalk C., 2000, Ozonation of water and waste water : a practical guide to understanding ozone and its application
[5]   ROLE OF HYDROXYL RADICAL REACTIONS IN OZONATION PROCESSES IN AQUEOUS-SOLUTIONS [J].
HOIGNE, J ;
BADER, H .
WATER RESEARCH, 1976, 10 (05) :377-386
[6]   Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment [J].
Kasprzyk-Hordern, B ;
Ziólek, M ;
Nawrocki, J .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 46 (04) :639-669
[7]   Elucidation of the molecular structure of hydrated vanadium oxide species by X-ray absorption spectroscopy:: correlation between the V•••V coordination number and distance and the point of zero charge of the support oxide [J].
Keller, Daphne E. ;
Koningsberger, Diek C. ;
Weckhuysen, Bert M. .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (41) :4814-4824
[8]   Ozonation of hydrolyzed azo dye reactive yellow 84 (CI) [J].
Koch, M ;
Yediler, A ;
Lienert, D ;
Insel, G ;
Kettrup, A .
CHEMOSPHERE, 2002, 46 (01) :109-113
[9]  
Ku Y, 2008, J ADV OXID TECHNOL, V11, P377
[10]  
Langlais B., 1991, Ozone in Water Treatment: Application and Engineering