Isolation of 1-tert-butyl-1,4-dihydro[60]fullerene, and its base-catalysed rearrangement to the 1,2-dihydro[60]fullerene analogue

被引：3

作者：

Banim, F ^{[1
]}

Cardin, DJ ^{[1
]}

Heath, P ^{[1
]}

机构：

[1] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1997年 / 58卷 / 11期

关键词：

D O I：

10.1016/S0022-3697(97)00078-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of tert-butyllithium with [60]fullerene followed by acid quench affords the 1-tert-butyl-1,4-dihydrofullerene, which can be isolated substantially pure. The solid material appear; to be indefinitely stable, but in solution undergoes base-catalysed rearrangement to the 1,2-isomer. The kinetics and energy of activation for this rearrangement are presented. (C) 1997 Elsevier Science Ltd.

引用

页码：1925 / 1927

页数：3