A Novel High-Entropy Amorphous Thin Film with High Electrical Resistivity and Outstanding Corrosion Resistance

被引:28
作者
Feng, Chuang-Shi [1 ,2 ]
Lu, Tian-Wei [1 ,3 ]
Wang, Tian-Li [1 ,2 ]
Lin, Man-Zhen [1 ]
Hou, Junhua [4 ]
Lu, Wenjun [4 ]
Liao, Wei-Bing [1 ]
机构
[1] Shenzhen Univ, Coll Phys & Optoelect Engn, Shenzhen 518060, Peoples R China
[2] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen 518060, Peoples R China
[3] City Univ Hong Kong, Dept Mat Sci & Engn, Hong Kong 999077, Peoples R China
[4] Southern Univ Sci & Technol, Dept Mech & Energy Engn, Shenzhen 518055, Peoples R China
基金
中国国家自然科学基金;
关键词
High-entropy alloys; Thin films; Electrical resistivity; Microstructures; Corrosion behaviors; SURFACE OXIDE-FILM; MECHANICAL-PROPERTIES; PASSIVE FILM; HIGH-STRENGTH; MO ALLOY; BEHAVIOR; XPS; MICROSTRUCTURE; VANADIUM; DEPOSITION;
D O I
10.1007/s40195-021-01255-9
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
This study explores a novel WNbMoTaV high-entropy thin film (HETF) in amorphous structure via pulsed laser deposition system. The formation of amorphous structure of this high-entropy alloy is ascribed to the high cooling rate during the deposition process. The HETF shows a smooth surface with a height fluctuation of less than 13 nm. This film has a high electrical resistivity of similar to 320.6 mu Omega.cm and a low corrosion current density of 0.088 mu A/cm(2). The corrosion resistance of the HETF at ambient temperature is superior to the conventional AISI 316L stainless steel. The high electrical resistivity and excellent corrosion resistance of the HETF are mainly attributed to its chemical disorder, cocktail effect and homogeneous amorphous structure. This experimental phenomenon not only provides a basis for the preparation of amorphous alloy films with low glass forming ability by pulsed laser deposition system, also promotes the potential application of WNbMoTaV HETF in the microelectronic components as resistivity sensors.
引用
收藏
页码:1537 / 1545
页数:9
相关论文
共 54 条
[21]   Combinatorial exploration of the High Entropy Alloy System Co-Cr-Fe-Mn-Ni [J].
Kauffmann, Alexander ;
Stueber, Michael ;
Leiste, Harald ;
Ulrich, Sven ;
Schlabach, Sabine ;
Szabo, Dorothee Vinga ;
Seils, Sascha ;
Gorr, Bronislava ;
Chen, Hans ;
Seifert, Hans-Juergen ;
Heilmaier, Martin .
SURFACE & COATINGS TECHNOLOGY, 2017, 325 :174-180
[22]   Mechanical and electrical properties of NbMoTaW refractory high-entropy alloy thin films [J].
Kim, Hanuel ;
Nam, Seungjin ;
Roh, Aeran ;
Son, Myungwoo ;
Ham, Moon-Ho ;
Kim, Jae-Hun ;
Choi, Hyunjoo .
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2019, 80 :286-291
[23]   Microstructural evolution and electrical resistivity of nanocrystalline W thin films grown by sputtering [J].
Kim, Yong Jin ;
Kang, Sung-Gyu ;
Oh, Yeonju ;
Kim, Gyu Won ;
Cha, In Ho ;
Han, Heung Nam ;
Kim, Young Keun .
MATERIALS CHARACTERIZATION, 2018, 145 :473-478
[24]   Cobalt-based alloys for orthopaedic applications studied by electrochemical and XPS analysis [J].
Kocijan, A ;
Milosev, I ;
Pihlar, B .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2004, 15 (06) :643-650
[25]   Status of pulsed laser deposition: challenges and opportunities [J].
Kuppusami, P ;
Raghunathan, VS .
SURFACE ENGINEERING, 2006, 22 (02) :81-83
[26]   High-temperature bulk metallic glasses developed by combinatorial methods [J].
Li, Ming-Xing ;
Zhao, Shao-Fan ;
Lu, Zhen ;
Hirata, Akihiko ;
Wen, Ping ;
Bai, Hai-Yang ;
Chen, MingWei ;
Schroers, Jan ;
Liu, YanHui ;
Wang, Wei-Hua .
NATURE, 2019, 569 (7754) :99-+
[27]   High Strength and Deformation Mechanisms of Al0.3CoCrFeNi High-Entropy Alloy Thin Films Fabricated by Magnetron Sputtering [J].
Liao, Wei-Bing ;
Zhang, Hongti ;
Liu, Zhi-Yuan ;
Li, Pei-Feng ;
Huang, Jian-Jun ;
Yu, Chun-Yan ;
Lu, Yang .
ENTROPY, 2019, 21 (02)
[28]   Nanocrystalline high-entropy alloy (CoCrFeNiAl0.3) thin-film coating by magnetron sputtering [J].
Liao, Weibing ;
Lan, Si ;
Gao, Libo ;
Zhang, Hongti ;
Xu, Shang ;
Song, Jian ;
Wang, Xunli ;
Lu, Yang .
THIN SOLID FILMS, 2017, 638 :383-388
[29]   Electrochemical Corrosion Behavior of Nanocrystalline β-Ta Coating for Biomedical Applications [J].
Liu, Lin Lin ;
Xu, Jiang ;
Lu, Xiaolin ;
Munroe, Paul ;
Xie, Zong-Han .
ACS BIOMATERIALS SCIENCE & ENGINEERING, 2016, 2 (04) :579-594
[30]   Microstructures and mechanical properties of CoCrFeNiAl0.3 high-entropy alloy thin films by pulsed laser deposition [J].
Lu, Tian-Wei ;
Feng, Chuang-Shi ;
Wang, Zheng ;
Liao, Kai-Wen ;
Liu, Zhi-Yuan ;
Xie, Yi-Zhu ;
Hu, Ju-Guang ;
Liao, Wei-Bing .
APPLIED SURFACE SCIENCE, 2019, 494 :72-79