A Novel High-Entropy Amorphous Thin Film with High Electrical Resistivity and Outstanding Corrosion Resistance

被引:28
作者
Feng, Chuang-Shi [1 ,2 ]
Lu, Tian-Wei [1 ,3 ]
Wang, Tian-Li [1 ,2 ]
Lin, Man-Zhen [1 ]
Hou, Junhua [4 ]
Lu, Wenjun [4 ]
Liao, Wei-Bing [1 ]
机构
[1] Shenzhen Univ, Coll Phys & Optoelect Engn, Shenzhen 518060, Peoples R China
[2] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen 518060, Peoples R China
[3] City Univ Hong Kong, Dept Mat Sci & Engn, Hong Kong 999077, Peoples R China
[4] Southern Univ Sci & Technol, Dept Mech & Energy Engn, Shenzhen 518055, Peoples R China
基金
中国国家自然科学基金;
关键词
High-entropy alloys; Thin films; Electrical resistivity; Microstructures; Corrosion behaviors; SURFACE OXIDE-FILM; MECHANICAL-PROPERTIES; PASSIVE FILM; HIGH-STRENGTH; MO ALLOY; BEHAVIOR; XPS; MICROSTRUCTURE; VANADIUM; DEPOSITION;
D O I
10.1007/s40195-021-01255-9
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
This study explores a novel WNbMoTaV high-entropy thin film (HETF) in amorphous structure via pulsed laser deposition system. The formation of amorphous structure of this high-entropy alloy is ascribed to the high cooling rate during the deposition process. The HETF shows a smooth surface with a height fluctuation of less than 13 nm. This film has a high electrical resistivity of similar to 320.6 mu Omega.cm and a low corrosion current density of 0.088 mu A/cm(2). The corrosion resistance of the HETF at ambient temperature is superior to the conventional AISI 316L stainless steel. The high electrical resistivity and excellent corrosion resistance of the HETF are mainly attributed to its chemical disorder, cocktail effect and homogeneous amorphous structure. This experimental phenomenon not only provides a basis for the preparation of amorphous alloy films with low glass forming ability by pulsed laser deposition system, also promotes the potential application of WNbMoTaV HETF in the microelectronic components as resistivity sensors.
引用
收藏
页码:1537 / 1545
页数:9
相关论文
共 54 条
[1]   ONE-DIMENSIONAL STEADY-STATE MODEL FOR DAMAGE BY VAPORIZATION AND LIQUID EXPULSION DUE TO LASER-MATERIAL INTERACTION [J].
CHAN, CL ;
MAZUMDER, J .
JOURNAL OF APPLIED PHYSICS, 1987, 62 (11) :4579-4586
[2]   Microstructural characterization of medium entropy alloy thin films [J].
Chawake, Niraj ;
Zalesak, Jakub ;
Gammer, Christoph ;
Franz, Robert ;
Cordill, Megan J. ;
Kim, Jeong Tae ;
Eckert, Juergen .
SCRIPTA MATERIALIA, 2020, 177 :22-26
[3]   High temperature electrical properties and oxidation resistance of V-Nb-Mo-Ta-W high entropy alloy thin films [J].
Chen, Yen-Yu ;
Hung, Sheng-Bo ;
Wang, Chaur-Jeng ;
Wei, Wen-Chung ;
Lee, Jyh-Wei .
SURFACE & COATINGS TECHNOLOGY, 2019, 375 :854-863
[4]   Corrosion of nanocrystalline Ni-W alloys in alkaline and acidic 3.5 wt.% NaCl solutions [J].
Chianpairot, Amnuaysak ;
Lothongkum, Gobboon ;
Schuh, Christopher A. ;
Boonyongmaneerat, Yuttanant .
CORROSION SCIENCE, 2011, 53 (03) :1066-1071
[5]   Effects of nanotwins on the mechanical properties of AlxCoCrFeNi high entropy alloy thin films [J].
Feng, X. B. ;
Fu, W. ;
Zhang, J. Y. ;
Zhao, J. T. ;
Li, J. ;
Wu, K. ;
Liu, G. ;
Sun, J. .
SCRIPTA MATERIALIA, 2017, 139 :71-76
[6]   Recent advances on environmental corrosion behavior and mechanism of high-entropy alloys [J].
Fu, Yu ;
Li, Jun ;
Luo, Hong ;
Du, Cuiwei ;
Li, Xiaogang .
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2021, 80 :217-233
[7]   Microstructure, Mechanical and Corrosion Behaviors of CoCrFeNiAl0.3 High Entropy Alloy (HEA) Films [J].
Gao, Libo ;
Liao, Weibing ;
Zhang, Hongti ;
Surjadi, James Utama ;
Sun, Dong ;
Lu, Yang .
COATINGS, 2017, 7 (10)
[8]   FAST INTENSIFIED-CCD PHOTOGRAPHY OF YBA2CU3O7-X LASER ABLATION IN VACUUM AND AMBIENT OXYGEN [J].
GEOHEGAN, DB .
APPLIED PHYSICS LETTERS, 1992, 60 (22) :2732-2734
[9]   Microstructure and mechanical properties of refractory MoNbHfZrTi high-entropy alloy [J].
Guo, N. N. ;
Wang, L. ;
Luo, L. S. ;
Li, X. Z. ;
Su, Y. Q. ;
Guo, J. J. ;
Fu, H. Z. .
MATERIALS & DESIGN, 2015, 81 :87-94
[10]   Molybdenum Effects on Pitting Corrosion Resistance of FeCrMnMoNC Austenitic Stainless Steels [J].
Ha, Heon-Young ;
Lee, Tae-Ho ;
Bae, Jee-Hwan ;
Chun, Dong Won .
METALS, 2018, 8 (08)