Amides of trivalent phosphorus acids as phosphorylating reagents for proton-donating nucleophiles

被引：100
作者：
Nifantiev, EE [1 ]
Grachev, MK [1 ]
Burmistrov, SY [1 ]
机构：
[1] VI Lenin Moscow State Pedag Univ, Dept Chem, Moscow 119021, Russia
来源：
CHEMICAL REVIEWS | 2000年 / 100卷 / 10期
关键词：
D O I：
10.1021/cr9601371
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Phosphorylating reagents includes the amides of trivalent phosphorus acids (ATPA). Phosphamide reagents differ from others due to the spatial organization of leaving amide group for selective phosphorylation of nucleophiles containing several reactive sites. The reagents also possess potential for selective phosphorylation of the primary hydroxyl.
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页码：3755 / 3799
页数：45
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