Structural and Chemical Evolution of the SOFC Anode La0.30Sr0.70Fe0.70Cr0.30O3-δ upon Reduction and Oxidation: An in Situ Neutron Diffraction Study

Although some perovskite oxides have been shown to be stable solid oxide fuel cell (SOFC) anodes, the actual crystal structure of these materials under operating conditions is largely unknown. In this paper, the structural evolution or the SOFC anode La0.30Sr0.70Fe0.70Cr0.30O3-delta was studied at 800 and 900 degrees C (similar to SOFC operating temperatures) in progressively reducimg and oxidizing environments. The perovskite was shown to be stable down to a pO(2) of 10(-20) atm at 800 degrees C and a pO(2) of 10(-18) atm at 900 degrees C, at which point a spinel phase formed. Further reduction led to the formation of Fe metal. The phase separation of La0.30Sr0.70Fe0.70Cr0.30O3-delta was also shown to be completely reversible with an increase in the partial oxygen pressure and reoxidation of the sample.