cis-Eudesmane sesquiterpene glycosides from Liriope muscari and Ophiopogon japonicus

被引:30
作者
Cheng, ZH
Wu, T
Bligh, SWA
Bashall, A
Yu, BY
机构
[1] London Metropolitan Univ, Inst Hlth Res & Policy, London N7 8DB, England
[2] China Pharmaceut Univ, Dept Complex Prescript Chinese Mat Med, Nanjing 210009, Peoples R China
[3] Shanghai Univ Tradit Chinese Med, Inst Chinese Mat Med, Shanghai 201203, Peoples R China
来源
JOURNAL OF NATURAL PRODUCTS | 2004年 / 67卷 / 10期
关键词
D O I
10.1021/np049864e
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
Two new cis-eudesmane sesquiterpene glycosides, liriopeoside A (1) and ophiopogonoside A (2), were extracted and purified from tubers of Liriope muscari and Ophiopogon japonicus, respectively, along with three known compounds. Their structures were elucidated as 1beta,6beta-dihydroxy-cis-eudesm-3-ene-6-O-beta-D-glucopyranoside (1) and 1beta,4beta,6beta-trihydroxy-cis-eudesmane-6-O-beta-D-glucopyranoside (2) by spectral data analysis. The structure and the relative configuration of compound 1 were confirmed by X-ray crystallographic analysis. This is the first time that cis-eudesmane-type sesquiterpenes have been reported from the genera Ophiopogon and Liriope.
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页码:1761 / 1763
页数:3
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