Kinetic separation of hexane isomers by fixed-bed adsorption with a microporous metal-organic framework

被引：172
作者：
Barcia, Patrick S.
Zapata, Fatima
Silva, Jose A. C.
Rodrigues, Alirio E.
Chen, Banglin [1 ]
机构：
[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA
[2] Inst Politecn Braganca, Escola Super Tecnol & Gestao, P-5301857 Braganca, SP, Portugal
[3] Univ Porto, Lab Separat & React Engn, Dept Engn Quim, P-4200465 Oporto, Portugal
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2007年 / 111卷 / 22期
关键词：
D O I：
10.1021/jp0721898
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A three-dimensional microporous metal-organic framework Zn(BDC)(Dabco)(0.5) (BDC = 1,4-benzenedicarboxylate, Dabco = 1,4-diazabicyclo [2,2,2]octane), having two types of intersecting pores to encapsulate linear hexane and to block branched hexanes, and thus exhibiting highly selective sorption with respect to n-hexane, has been successfully applied to the kinetic separation of hexane isomers by fixed-bed adsorption.
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收藏
页码：6101 / 6103
页数：3
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