An unprecedented Zn10O4 heteroadamantane cage containing anilido-pyridinate ligand and its activity for ring opening polymerization of L-lactide and ε-caprolactone

被引：13
作者：
Chen, Ming-Tsz [1 ]
Chen, Chi-Tien [2 ]
机构：
[1] Providence Univ, Dept Appl Chem, Taichung 43301, Taiwan
[2] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan
来源：
DALTON TRANSACTIONS | 2017年 / 46卷 / 31期
关键词：
ZINC-OXIDE CLUSTERS; MAIN-GROUP; COMPLEXES; CATALYSTS; OXAZOLINATE; COORDINATION; ASSEMBLIES;
D O I：
10.1039/c7dt01925d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
(NPyC2OMe)(8)Zn10Et4(mu(4)-O)(4) (1) has been synthesized in situ by hydrolysis of ZnEt2 in a one pot process and it was proved by applying X-ray structure analysis that the organozinc anilido-pyridinate moiety encapsulated the zinc oxide cluster, which demonstrated one self-assembled coordinate mode "Zn10O4". Moreover, the catalytic activity was investigated and good activity for L-lactide and epsilon-caprolactone ring opening polymerization was observed with both living and controllable properties.
引用
收藏
页码：10181 / 10184
页数：4
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