Mechanism of ion transfer in structure-disordered copper and silver chalcogenides

被引：9

作者：

Bikkulova, N. N. ^{[1
]}

Stepanov, Yu. M. ^{[1
]}

Mikolaichuk, A. N. ^{[1
]}

机构：

[1] Sterlitamak State Educ Acad, Sterlitamak 453103, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2007年 / 43卷 / 05期

关键词：

ion transfer; superionic conductors; copper chalcogenides; silver chalcogenides; crystal structure; lattice dynamics;

D O I：

10.1134/S1023193507050151

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Copper and silver selenides and tellurides and their solid solutions are studied. Parameters of ion transfer are measured; the solid solution structure is refined using x-ray and neutron diffraction analysis; the lattice dynamics is studied using the neutron inelastic scattering and NMR; and the short-range order is studied using EXAFS. Based on the summarizing of the experimental results obtained, in aggregate with literature data, a physical mechanism of ion transfer in mixed ion-electron conductors is suggested.

引用

页码：595 / 597

页数：3

共 9 条

[1] Interaction between crystal lattice and mobile ions in copper selenides studied by EXAFS spectroscopy
Asylgushina, GN
Bikkulova, NN
Titova, SG
Kochubey, DI
[J]. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2005, 543 (01) : 194 - 195
[2] [Биккулова Н.Н. Bikkulova N.N.], 2005, [Известия Российской академии наук. Серия физическая, Bulletin of the Russian Academy of Sciences: Physics, Izvestiya Rossiiskoi akademii nauk. Seriya fizicheskaya], V69, P939
[3] BIKKULOVA NN, 2003, IZV AKAD NAUK FIZ+, V67, P915
[4] BIKKULOVA NN, 2004, IZV AKAD NAUK FIZ+, V68, P604
[5] BIKKULOVA NN, 2003, KRISTALLOGRAFIYA, V48, P414
[6] Ivanov-Shits A.K., 2000, Solid State Ionics, V1
[7] MIYATANI S, 1973, J PHYS SOC JPN, V34, P422
[8] POLYAKOV VI, 2001, FIZ TVERD TELA, V43, P630
[9] INVESTIGATIONS ON SILVER SULFIDE
WAGNER, C
[J]. JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (10) : 1819 - 1827

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