Micrometer-sized spherical assemblies of polypeptides and small molecules by acid-base chemistry

被引：50
作者：
McKenna, BJ
Birkedal, H [1 ]
Bartl, MH
Deming, TJ
Stucky, GD
机构：
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Calif Nanosyst Inst, Santa Barbara, CA 93106 USA
[3] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 42期
关键词：
colloids; hybrid materials; polymers; self-assembly; template synthesis;
D O I：
10.1002/anie.200460510
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Spontaneous formation of microspheres is observed when charged poly(amino acid)s are combined with certain oppositely charged, multivalent organic ions. The surfaces of the spheres are chemically active and act as templates for silica condensation, and the assemblies can be made hollow or polymer-filled, depending on the silica precursor (see image; the fluorescent polymer forms a layer inside a colloidal-silica-coated sphere).
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收藏
页码：5652 / 5655
页数：4
相关论文
共 34 条
[1]   Simple model for attraction between like-charged polyions [J].
Arenzon, JJ ;
Stilck, JF ;
Levin, Y .
EUROPEAN PHYSICAL JOURNAL B, 1999, 12 (01) :79-82
[2]   Electrostatic free energy of weakly charged macromolecules in solution and intermacromolecular complexes consisting of oppositely charged polymers [J].
Biesheuvel, PM ;
Stuart, MAC .
LANGMUIR, 2004, 20 (07) :2785-2791
[3]   Biomimetic synthesis of silica nanospheres depends on the aggregation and phase separation of polyamines in aqueous solution [J].
Brunner, E ;
Lutz, K ;
Sumper, M .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (04) :854-857
[4]   Formation of mono-sized polyelectrolyte complex dispersions: effects of polymer structure, concentration and mixing conditions [J].
Buchhammer, HM ;
Mende, M ;
Oelmann, M .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2003, 218 (1-3) :151-159
[5]   Biomimetic synthesis of ordered silica structures mediated by block copolypeptides [J].
Cha, JN ;
Stucky, GD ;
Morse, DE ;
Deming, TJ .
NATURE, 2000, 403 (6767) :289-292
[6]   Spontaneous formation of nanoparticle vesicles from homopolymer polyelectrolytes [J].
Cha, JN ;
Birkedal, H ;
Euliss, LE ;
Bartl, MH ;
Wong, MS ;
Deming, TJ ;
Stucky, GD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (27) :8285-8289
[7]   Microcavity lasing from block peptide hierarchically assembled quantum dot spherical resonators [J].
Cha, JN ;
Bartl, MH ;
Wong, MS ;
Popitsch, A ;
Deming, TJ ;
Stucky, GD .
NANO LETTERS, 2003, 3 (07) :907-911
[8]  
Chécot F, 2002, ANGEW CHEM INT EDIT, V41, P1339, DOI 10.1002/1521-3773(20020415)41:8<1339::AID-ANIE1339>3.0.CO
[9]  
2-N
[10]  
Checot F., 2002, ANGEW CHEM, V114, P1395
1234