Preparation of phenolic chiral crown ethers and podands and their enantiomer recognition ability toward secondary amines

被引：31
|
作者：
Hirose, K [1 ]
Fujiwara, A
Matsunaga, K
Aoki, N
Tobe, Y
机构：
[1] Osaka Univ, Fac Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan
[2] Japan Sci & Technol Corp, JST, CREST, Toyonaka, Osaka 5608531, Japan
来源：
TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 05期
关键词：
ENANTIOSELECTIVE COMPLEXATION; DERIVATIVES; 2,4-DIMETHYL-3-OXAPENTANE-1,5-DIOL; RECEPTORS; BEHAVIOR; BINDING; SUBUNIT; DRUGS;
D O I：
10.1016/S0957-4166(03)00031-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Phenolic pseudo-24-crown-8 (S,S)-3, pseudo-27-crown-9 (S,S)-4, and podands (R,R)-5 and (R,R)-6 possessing phenyl groups as chiral barriers were prepared and their chiral recognition properties toward secondary neutral amines were examined. Pseudo-24-crown-8 (S,S)-3 and podand (R,R)-5 showed sufficient binding ability and moderate chiral recognition ability toward secondary amines. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：555 / 566
页数：12
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