Polarization-Induced Hole Doping in Wide-Band-Gap Uniaxial Semiconductor Heterostructures

被引:688
作者
Simon, John [1 ]
Protasenko, Vladimir [1 ]
Lian, Chuanxin [1 ]
Xing, Huili [1 ]
Jena, Debdeep [1 ]
机构
[1] Univ Notre Dame, Dept Elect Engn, Notre Dame, IN 46556 USA
基金
美国国家科学基金会;
关键词
LIGHT-EMITTING-DIODES;
D O I
10.1126/science.1183226
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Impurity-based p-type doping in wide-band-gap semiconductors is inefficient at room temperature for applications such as lasers because the positive-charge carriers (holes) have a large thermal activation energy. We demonstrate high-efficiency p-type doping by ionizing acceptor dopants using the built-in electronic polarization in bulk uniaxial semiconductor crystals. Because the mobile hole gases are field-ionized, they are robust to thermal freezeout effects and lead to major improvements in p-type electrical conductivity. The new doping technique results in improved optical emission efficiency in prototype ultraviolet light-emitting-diode structures. Polarization-induced doping provides an attractive solution to both p-and n-type doping problems in wide-band-gap semiconductors and offers an unconventional path for the development of solid-state deep-ultraviolet optoelectronic devices and wide-band-gap bipolar electronic devices of the future.
引用
收藏
页码:60 / 64
页数:5
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