Fabrication of Superhydrophobic Cellulose/Chitosan Composite Aerogel for Oil/Water Separation

被引:86
作者
Meng, Guihua [1 ]
Peng, Huili [1 ]
Wu, Jianning [1 ]
Wang, Yixi [1 ]
Wang, Hao [1 ]
Liu, Zhiyong [1 ]
Guo, Xuhong [1 ]
机构
[1] Shihezi Univ, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Engn Res Ctr Mat Oriented Chem Engn Xinjiang Bing, Sch Chem & Chem Engn,Key Lab Mat Oriented Chem En, Xinjiang 832003, Peoples R China
基金
中国国家自然科学基金;
关键词
Rough surface; Cellulose and chitosan composite aerogel; Superhydrophobic; Oil-water separation; OIL-WATER SEPARATION; SPONGES; CHITOSAN; SURFACE; ROBUST; ABSORPTION; DEPOSITION; ABSORBENT; EFFICIENT;
D O I
10.1007/s12221-017-1099-4
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
Superhydrophobic cellulose and chitosan composite aerogel (SCECS) is fabricated through a novel and simple approach for the first time. During the preparation of cellulose and chitosan composite aerogel (CECS), chitosan is self assemble into number micron-diameter particles on the surface of aerogel, which is similar to the micromorphology of a lotus leaf. Based on the rough surface, CECS is modified by sodium stearate through electrostatic interaction and ion exchange. Water contact angles of 156 degrees are obtained for superhydrophobic aerogel. SCECS can remove various oils from water and with absorption capacities of 10 g/g for oil. Furthermore, the special structure of a non-porous of surface and porous layer of internal is benefit to separate surfactant-stabilized water-in-oil emulsions under gravity.
引用
收藏
页码:706 / 712
页数:7
相关论文
共 24 条
[1]   Chitosan, sisal cellulose, and biocomposite chitosan/sisal cellulose films prepared from thiourea/NaOH aqueous solution [J].
Almeida, E. V. R. ;
Frollini, E. ;
Castellan, A. ;
Coma, V. .
CARBOHYDRATE POLYMERS, 2010, 80 (03) :655-664
[2]   Hydrophobic Modification on Surface of Chitin Sponges for Highly Effective Separation of Oil [J].
Duan, Bo ;
Gao, Huimin ;
He, Meng ;
Zhang, Lina .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (22) :19933-19942
[3]   Study of Factors Governing Oil-Water Separation Process Using TiO2 Films Prepared by Spray Deposition of Nanoparticle Dispersions [J].
Gondal, Mohammed A. ;
Sadullah, Muhammad S. ;
Dastageer, Mohamed A. ;
McKinley, Gareth H. ;
Panchanathan, Divya ;
Varanasi, Kripa K. .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (16) :13422-13429
[4]   Mussel-Inspired One-Step Copolymerization to Engineer Hierarchically Structured Surface with Superhydrophobic Properties for Removing Oil from Water [J].
Huang, Shouying .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (19) :17144-17150
[5]   A Rapid One-Step Fabrication of Patternable Superhydrophobic Surfaces Driven by Marangoni Instability [J].
Kang, Sung-Min ;
Hwang, Sora ;
Jin, Si-Hyung ;
Choi, Chang-Hyung ;
Kim, Jongmin ;
Park, Bum Jun ;
Lee, Daeyeon ;
Lee, Chang-Soo .
LANGMUIR, 2014, 30 (10) :2828-2834
[6]   Oil/Water Separation Performances of Superhydrophobic and Superoleophilic Sponges [J].
Ke, Qingping ;
Jin, Yangxin ;
Jiang, Peng ;
Yu, Jian .
LANGMUIR, 2014, 30 (44) :13137-13142
[7]   Hydrophobic Nanocellulose Aerogels as Floating, Sustainable, Reusable, and Recyclable Oil Absorbents [J].
Korhonen, Juuso T. ;
Kettunen, Marjo ;
Ras, Robin H. A. ;
Ikkala, Olli .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (06) :1813-1816
[8]   Carbon Aerogel from Winter Melon for Highly Efficient and Recyclable Oils and Organic Solvents Absorption [J].
Li, Yuan-Qing ;
Samad, Yarjan Abdul ;
Polychronopoulou, Kyriaki ;
Alhassan, Saeed M. ;
Liao, Kin .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2014, 2 (06) :1492-1497
[9]   Stable superhydrophobic and superoleophilic soft porous materials for oil/water separation [J].
Liang, Weixin ;
Guo, Zhiguang .
RSC ADVANCES, 2013, 3 (37) :16469-16474
[10]   Hydrophobic and flexible cellulose aerogel as an efficient, green and reusable oil sorbent [J].
Lin, Runjun ;
Li, Ang ;
Zheng, Tingting ;
Lu, Lingbin ;
Cao, Yang .
RSC ADVANCES, 2015, 5 (100) :82027-82033