Rational design of atomically dispersed nickel active sites in β-Mo2C for the hydrogen evolution reaction at all pH values

被引：108

作者：

Ouyang, Ting ^{[1
]}

Chen, An-Na ^{[1
]}

He, Zhen-Zhao ^{[1
]}

Liu, Zhao-Qing ^{[1
]}

Tong, Yexiang ^{[2
]}

机构：

[1] Guangzhou Univ, Minist Educ, Sch Chem & Chem Engn,Guangzhou Higher Educ Mega C, Key Lab Water Qual & Conservat Pearl River Delta, Outer Ring Rd 230, Guangzhou 510006, Guangdong, Peoples R China

[2] Sun Yat Sen Univ, MOE, Key Lab Bioinorgan & Synthet Chem,Sch Chem, Key Lab Low Carbon Chem & Energy Conservat Guangd, 135 Xingang West Rd, Guangzhou 510275, Guangdong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 71期

关键词：

NITROGEN-DOPED CARBON; MOLYBDENUM-CARBIDE; HIGHLY EFFICIENT; ELECTROCATALYSTS; NANOWIRES; CATALYST; MO2C;

D O I：

10.1039/c8cc03975e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Atomically dispersed Ni species on beta-Mo2C (Ni/(beta-Mo2C) is designed and synthesized through a simple thermal treatment process. Benefitting from the synergistic effect between Ni species and beta-Mo2C, Ni/beta-Mo2C exhibits high activities for the HER at all pH values.

引用

页码：9901 / 9904

页数：5

共 37 条

[1] Efficient and Stable Bifunctional Electrocatalysts Ni/NixMy (M = P, S) for Overall Water Splitting [J].

Chen, Gao-Feng ;

Ma, Tian Yi ;

Liu, Zhao-Qing ;

Li, Nan ;

Su, Yu-Zhi ;

Davey, Kenneth ;

Qiao, Shi-Zhang .

ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (19) :3314-3323

[2] Rational Design of Single Molybdenum Atoms Anchored on N-Doped Carbon for Effective Hydrogen Evolution Reaction [J].

Chen, Wenxing ;

Pei, Jiajing ;

He, Chun-Ting ;

Wan, Jiawei ;

Ren, Hanlin ;

Zhu, Youqi ;

Wang, Yu ;

Dong, Juncai ;

Tian, Shubo ;

Cheong, Weng-Chon ;

Lu, Siqi ;

Zheng, Lirong ;

Zheng, Xusheng ;

Yan, Wensheng ;

Zhuang, Zhongbin ;

Chen, Chen ;

Peng, Qing ;

Wang, Dingsheng ;

Li, Yadong .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (50) :16086-16090

[3] Highly Active, Nonprecious Electrocatalyst Comprising Borophene Subunits for the Hydrogen Evolution Reaction [J].

Chen, Yanli ;

Yu, Guangtao ;

Chen, Wei ;

Liu, Yipu ;

Li, Guo-Dong ;

Zhu, Pinwen ;

Tao, Qiang ;

Li, Qiuju ;

Liu, Jingwei ;

Shen, Xiaopeng ;

Li, Hui ;

Huang, Xuri ;

Wang, Dejun ;

Asefa, Tewodros ;

Zou, Xiaoxin .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (36) :12370-12373

[4] Self-Templated Fabrication of MoNi4/MoO3-X Nanorod Arrays with Dual Active Components for Highly Efficient Hydrogen Evolution [J].

Chen, Yu-Yun ;

Zhang, Yun ;

Zhang, Xing ;

Tang, Tang ;

Luo, Hao ;

Niu, Shuai ;

Dai, Zhi-Hui ;

Wan, Li-Jun ;

Hu, Jin-Song .

ADVANCED MATERIALS, 2017, 29 (39)

[5] Interacting ZnCo2O4 and Au nanodots on carbon nanotubes as highly efficient water oxidation electrocatalyst [J].

Cheng, Hui ;

Su, Chang-Yuan ;

Tan, Zhi-Yun ;

Tai, Su-Zhen ;

Liu, Zhao-Qing .

JOURNAL OF POWER SOURCES, 2017, 357 :1-10

[6] Raman spectroscopy as a versatile tool for studying the properties of graphene [J].

Ferrari, Andrea C. ;

Basko, Denis M. .

NATURE NANOTECHNOLOGY, 2013, 8 (04) :235-246

[7] Achieving the Widest Range of Syngas Proportions at High Current Density over Cadmium Sulfoselenide Nanorods in CO2 Electroreduction [J].

He, Rong ;

Zhang, An ;

Ding, Yilun ;

Kong, Taoyi ;

Xiao, Qing ;

Li, Hongliang ;

Liu, Yan ;

Zeng, Jie .

ADVANCED MATERIALS, 2018, 30 (07)

[8] Ultrathin NiCo2Px nanosheets strongly coupled with CNTs as efficient and robust electrocatalysts for overall water splitting [J].

Huang, Can ;

Ouyang, Ting ;

Zou, Ying ;

Li, Nan ;

Liu, Zhao-Qing .

JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (17) :7420-7427

[9] Hollow Cobalt-Based Bimetallic Sulfide Polyhedra for Efficient All-pH-Value Electrochemical and Photocatalytic Hydrogen Evolution [J].

Huang, Zhen-Feng ;

Song, Jiajia ;

Li, Ke ;

Tahir, Muhammad ;

Wang, Yu-Tong ;

Pan, Lun ;

Wang, Li ;

Zhang, Xiangwen ;

Zou, Ji-Jun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (04) :1359-1365

[10] Hollow Chevrel-Phase NiMo3S4 for Hydrogen Evolution in Alkaline Electrolytes [J].

Jiang, Jun ;

Gao, Minrui ;

Sheng, Wenchao ;

Yan, Yushan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (49) :15240-15245

← 1 2 3 4 →