Alkoxides of o-silyl benzyl alcohols in cleavage reactions:: approaches to benzyl and silyl anion equivalents

被引：22

作者：

Hudrlik, PF ^{[1
]}

Arango, JO

Hijji, YM

Okoro, CO

Hudrlik, AM

机构：

[1] Howard Univ, Dept Chem, Washington, DC 20059 USA

[2] Morgan State Univ, Dept Chem, Baltimore, MD 21251 USA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 2000年 / 78卷 / 11期

关键词：

silyl migration; benzyl anion equivalent; silyl anion equivalent; beta-silyl ketone; gamma-hydroxysilane;

D O I：

10.1139/cjc-78-11-1421

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The alkoxides of o-silyl benzyl alcohols 4 undergo cleavage reactions under mild conditions allowing transfer of a benzyl or silyl group to an electrophile. Reactions 3a --> 8, and 3c or 4c --> 11 illustrate their potential as benzyl and silyl anion equivalents.

引用

页码：1421 / 1427

页数：7

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[3]

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