Layered H0.68Ti1.83O4/reduced graphene oxide nanosheets as a novel cathode for rechargeable magnesium batteries

被引:14
作者
Chen, Chengcheng [1 ,2 ]
Sun, Jianchao [3 ]
Miao, Licheng [1 ]
Yan, Zhenhua [1 ]
Chen, Jun [1 ]
机构
[1] Nankai Univ, Coll Chem, Minist Educ, Renewable Energy Convers & Storage Ctr,Key Lab Ad, Tianjin 300071, Peoples R China
[2] China Elect Prod Reliabil & Environm Testing Res, Guangzhou 510610, Guangdong, Peoples R China
[3] Yantai Univ, Sch Environm & Mat Engn, Yantai 264000, Shandong, Peoples R China
基金
国家重点研发计划; 中国国家自然科学基金;
关键词
HIGH-PERFORMANCE; VANADIUM-OXIDE; ELECTRODES; ANODE; WATER;
D O I
10.1039/c9cc07012e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rechargeable magnesium batteries (RMBs) are promising devices for energy storage owing to their high volumetric energy density and high safety, but they still suffer from the lack of suitable cathodes. Herein, we report the development of ultrathin hydrated H0.68Ti1.83O4/reduced graphene oxide nanosheet composite (HTO/rGO) as a novel cathode for RMBs. The HTO/rGO, strongly combining ultrathin HTO nanosheets (5 nm in thickness with large interlayer spacing of 0.93 nm) and high electronic conductivity of rGO performs quick Mg2+ kinetics with high reversibility and considerable capacity of 182 mA h g(-1), undergo an intercalation type reaction.
引用
收藏
页码:14578 / 14581
页数:4
相关论文
共 30 条
[1]   Prototype systems for rechargeable magnesium batteries [J].
Aurbach, D ;
Lu, Z ;
Schechter, A ;
Gofer, Y ;
Gizbar, H ;
Turgeman, R ;
Cohen, Y ;
Moshkovich, M ;
Levi, E .
NATURE, 2000, 407 (6805) :724-727
[2]   RAMAN-SPECTRA OF TITANIUM-DIOXIDE [J].
BALACHANDRAN, U ;
EROR, NG .
JOURNAL OF SOLID STATE CHEMISTRY, 1982, 42 (03) :276-282
[3]   Magnesium-Antimony Liquid Metal Battery for Stationary Energy Storage [J].
Bradwell, David J. ;
Kim, Hojong ;
Sirk, Aislinn H. C. ;
Sadoway, Donald R. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (04) :1895-1897
[4]   Two-Dimensional Titanium Carbide MXene As a Cathode Material for Hybrid Magnesium/Lithium-Ion Batteries [J].
Byeon, Ayeong ;
Zhao, Meng-Qiang ;
Ren, Chang E. ;
Halim, Joseph ;
Kota, Sankalp ;
Urbankowski, Patrick ;
Anasori, Babak ;
Barsoum, Michel W. ;
Gogotsi, Yury .
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (05) :4296-4300
[5]   Building highly stable and industrial NaVPO4F/C as bipolar electrodes for high-rate symmetric rechargeable sodium-ion full batteries [J].
Chen, Chengcheng ;
Li, Tianjiao ;
Tian, Han ;
Zou, Yabing ;
Sun, Jianchao .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (31) :18451-18457
[6]   Layered Na2Ti3O7/MgNaTi3O7/Mg0.5NaTi3O7 Nanoribbons as High-Performance Anode of Rechargeable Mg-Ion Batteries [J].
Chen, Chengcheng ;
Wang, Jianbin ;
Zhao, Qing ;
Wang, Yijing ;
Chen, Jun .
ACS ENERGY LETTERS, 2016, 1 (06) :1165-1172
[7]   Promise and reality of post-lithium-ion batteries with high energy densities [J].
Choi, Jang Wook ;
Aurbach, Doron .
NATURE REVIEWS MATERIALS, 2016, 1 (04)
[8]   Screening for positive electrodes for magnesium batteries: a protocol for studies at elevated temperatures [J].
Duffort, Victor ;
Sun, Xiaoqi ;
Nazar, Linda F. .
CHEMICAL COMMUNICATIONS, 2016, 52 (84) :12458-12461
[9]  
Li Y., 2019, CHEM, V5, P1
[10]   Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage [J].
Liang, Yanliang ;
Yoo, Hyun Deog ;
Li, Yifei ;
Shuai, Jing ;
Calderon, Hector A. ;
Hernandez, Francisco Carlos Robles ;
Grabow, Lars C. ;
Yao, Yan .
NANO LETTERS, 2015, 15 (03) :2194-2202