Solid acid catalysts for synthesis of biodiesel fuel from pyrolyzed natural and synthetic polymeric materials

被引:4
作者
Fedorishin, A. S. [1 ]
Strelko, V. V. [1 ]
Stavitskaya, S. S. [1 ]
Yakovlev, V. I. [1 ]
Tsyba, N. N. [1 ]
Mil'grandt, V. G. [1 ]
机构
[1] Natl Acad Sci Ukraine, Inst Sorpt & Endoecol Problems, Kiev, Ukraine
关键词
TRANSESTERIFICATION; ESTERIFICATION; ZIRCONIA;
D O I
10.1134/S1070427210020187
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
New heterogeneous catalysts for synthesis of a biodiesel fuel, modified with strongly acidic groups, were developed. The catalysts are produced by pyrolysis and subsequent sulfation of fruit kernels and granulated porous copolymers and resins. The structural-sorption and catalytic properties of the materials obtained were studied in the reaction of catalytic re-esterification of rapeseed oil by methanol and ethanol. The conditions in which carbon materials with high content of surface acid groups are obtained were optimized.
引用
收藏
页码:281 / 286
页数:6
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