A new multifunctional initiator system for the living cationic polymerization of vinyl ethers

被引：0

作者：

Zhang, XC

Goethals, EJ

Loontjens, T

Derks, F

机构：

[1] State Univ Ghent, Dept Organ Chem, Div Polymer Chem, B-9000 Ghent, Belgium

[2] DSM Res BV, NL-6160 MD Geleen, Netherlands

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2000年 / 21卷 / 08期

关键词：

D O I：

10.1002/(SICI)1521-3927(20000501)21:8<472::AID-MARC472>3.0.CO;2-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Communication: Combination of hexa(chloromethyl)melamine (HCMM) and zinc chloride was found to be a multifunctional initiator system for the living cationic polymerization of isobutyl vinyl ether. HCMM was synthesized by reaction of hexa(methoxymethyl)melamine and boron trichloride. Characterization of the polymers by means of GPC and H-1 NMR showed that initiation was rapid and quantitative and that the initiator is hexafunctional, leading to six-armed star-shaped polymers.

引用

页码：472 / 475

页数：4

共 8 条

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