Synthesis and characterization of (CpRu)3Co(CO)2(μ3-CO)B3H3 (Cp = η5-C5Me5):: A metallaborane with cubane cluster structure

被引：16

作者：

Lei, XJ ^{[1
]}

Shang, MY ^{[1
]}

Fehlner, TP ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 22期

关键词：

D O I：

10.1021/om000633m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Addition of a cobalt carbonyl fragment to (Cp*Ru)(3)(mu -N)(2)B3H6 leads to hydrogen loss and formation of the highly condensed (Cp*Ru)(3)Co(CO)(2)(mu3-CO)-B3H3 cluster. Viewed as a 60-electron tetranuclear metal cluster with six M-M bonds, it completes the series: 64-electron (CpCo)(4)B4H4 with four M-M bonds; 68-electron (CpNi)(4)B4R4 with two M-M bonds.

引用

页码：4429 / 4431

页数：3

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Synthesis and characterization of (Cp*Ru)3Co(CO)2(μ3-CO)B3H3 (Cp* = η5-C5Me5):: A metallaborane with cubane cluster structure

Synthesis and characterization of (CpRu)3Co(CO)2(μ3-CO)B3H3 (Cp = η5-C5Me5):: A metallaborane with cubane cluster structure