Synthesis and characterization of (Cp*Ru)3Co(CO)2(μ3-CO)B3H3 (Cp* = η5-C5Me5):: A metallaborane with cubane cluster structure

被引：16
|
作者：
Lei, XJ [1 ]
Shang, MY [1 ]
Fehlner, TP [1 ]
机构：
[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
来源：
ORGANOMETALLICS | 2000年 / 19卷 / 22期
关键词：
D O I：
10.1021/om000633m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Addition of a cobalt carbonyl fragment to (Cp*Ru)(3)(mu -N)(2)B3H6 leads to hydrogen loss and formation of the highly condensed (Cp*Ru)(3)Co(CO)(2)(mu3-CO)-B3H3 cluster. Viewed as a 60-electron tetranuclear metal cluster with six M-M bonds, it completes the series: 64-electron (CpCo)(4)B4H4 with four M-M bonds; 68-electron (CpNi)(4)B4R4 with two M-M bonds.
引用
收藏
页码：4429 / 4431
页数：3
相关论文
共 50 条
  • [21] Synthesis and structure of the metallaborane Cp*3(μ-H)W3B8H8 from the thermolysis of Cp*H3WB4H8 (Cp* = η5-C5Me5).: A close-packed 11-atom boron-rich cluster
    Weller, AS
    Shang, MY
    Fehlner, TP
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (32) : 8283 - 8284
  • [22] Syntheses of Ir4(CO)6(5-C5Me4H)2 and Ir7(3-CO)3(CO)12(5-C5Me5) from Pentametallic Molybdenum-Iridium Cluster Precursors
    Fu, Junhong
    Randles, Michael D.
    Criddle, Alan L.
    Moxey, Graeme J.
    Schwich, Torsten
    Stranger, Robert
    Cifuentes, Marie P.
    Humphrey, Mark G.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (15) : 2587 - 2591
  • [23] Cyclopentadienyl molybdenum dicarbonyl η3-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp′Mo(CO)2(η3-C3H5) (Cp′ = η5-C5H4Me, η5-C5Me5)
    Neves, Patricia
    Pereira, Claudia C. L.
    Paz, Filipe A. Almeida
    Gago, Sandra
    Pillinger, Martyn
    Silva, Carlos M.
    Valente, Anabela A.
    Romao, Carlos C.
    Goncalves, Isabel S.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (21) : 2311 - 2319
  • [24] The reaction of P4 with [Cp′Mo(CO)3]2 (Cp′ = η5-C5H4tBu) -: the structure of [Cp′Mo(CO)2⟨(η3-P4){Cr(CO)5}4(H)⟩]
    Scheer, M
    Becker, U
    Magull, J
    POLYHEDRON, 1998, 17 (11-12) : 1983 - 1989
  • [25] Synthesis and characterization of transition metal stabilized carbocations of the types [CP*(CO)2Fe{μ-(CnH2n-1}M(CO)xCp]PF6 (x=2, M = Fe or Ru; x=3, M = W, Cp* = η5-C5(CH3)5; Cp = η5-C5H5; n=3-6) and [Cp(CO)2Ru{μ-(CnH2n-1)}W(CO)3Cp]PF6 (n=3-5) and the crystal structures of the complexes [Cp*(CO)2Fe(CH2)3Ru(CO)2Co], [Cp*(CO)2Fe(CH2)5Ru(CO)2Cp], [Cp*(CO)2Fe-(CH2)5W(CO)3Cp], and [Cp(CO)2Ru(CH2)5W(CO)3Cp]
    Changamu, Evans O.
    Friedrich, Holger B.
    Rademeyer, Melanie
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (12) : 2456 - 2472
  • [26] METAL FRAGMENT ADDITION AND SUBSTITUTION-REACTIONS OF [RU3(CO)9BH5] AND [RU3H(CO)9(B2H5)] - MOLECULAR-STRUCTURES OF [WRU3(CP)H(CO)11(BH)] AND [MORU3(CP)H3(CO)11] (CP = ETA-C5H5)
    HOUSECROFT, CE
    MATTHEWS, DM
    RHEINGOLD, AL
    SONG, XJ
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (19): : 2855 - 2864
  • [27] Synthesis and characterization of the [Ru(η5-C5Me4CF3)(CO)2]2 and Ru6(μ3-H)(η2-μ4-CO)2(μ-CO)(CO)12(η5-C5Me4CF3) complexes
    Z. A. Kerzina
    M. I. Rybinskaya
    F. M. Dolgushin
    A. I. Yanovsky
    P. V. Petrovskii
    E. Kolehmainen
    Russian Chemical Bulletin, 1998, 47 : 490 - 495
  • [28] Synthesis and characterization of the [Ru(η5-C5Me4CF3)(CO)2]2 and Ru6(μ3-H)(η2-μ4-CO)2(μ-CO)(CO)12(η5-C5Me4CF3) complexes
    Kerzina, ZA
    Rybinskaya, MI
    Dolgushin, FM
    Yanovsky, AI
    Petrovskii, PV
    Kolehmainen, E
    RUSSIAN CHEMICAL BULLETIN, 1998, 47 (03) : 490 - 495
  • [29] Nitrogen-nitrogen bond cleavage of hydrazine derivatives by a trinuclear pentahydride complex of ruthenium, (Cp′Ru)3(μ-H)3(μ3-H)2 (Cp′ = η5-C5Me5)
    Nakajima, Y
    Suzuki, H
    ORGANOMETALLICS, 2003, 22 (05) : 959 - 969
  • [30] Construction of heterometallic Cubanes [{Ti3Cp*3(μ3-CR)}(μ 3-O)3{Mo(CO)3}] (R=H, Me; Cp*=η5-C5Me5) and [{Ti3Cp*3(μ3-N)}(μ 3-NH)3{M(CO)3}] (M=Cr, Mo, W); crystal structure.
    2000, Wiley-VCH Verlag (39):
12345