Synthesis and characterization of (Cp*Ru)3Co(CO)2(μ3-CO)B3H3 (Cp* = η5-C5Me5):: A metallaborane with cubane cluster structure

被引：16
|
作者：
Lei, XJ [1 ]
Shang, MY [1 ]
Fehlner, TP [1 ]
机构：
[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA
来源：
ORGANOMETALLICS | 2000年 / 19卷 / 22期
关键词：
D O I：
10.1021/om000633m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Addition of a cobalt carbonyl fragment to (Cp*Ru)(3)(mu -N)(2)B3H6 leads to hydrogen loss and formation of the highly condensed (Cp*Ru)(3)Co(CO)(2)(mu3-CO)-B3H3 cluster. Viewed as a 60-electron tetranuclear metal cluster with six M-M bonds, it completes the series: 64-electron (CpCo)(4)B4H4 with four M-M bonds; 68-electron (CpNi)(4)B4R4 with two M-M bonds.
引用
收藏
页码：4429 / 4431
页数：3
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