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Synthesis, Characterization and Antibacterial Properties of Nano-Porous Zn3(BTC)2•12H2O upon Silk Yarn Under Ultrasound Irradiation
被引:13
作者:
Abbasi, Amir Reza
[1
]
Noori, Nourolah
[1
]
机构:
[1] Razi Univ, Fac Chem, Kermanshah 67194, Iran
基金:
美国国家科学基金会;
关键词:
Nanoparticle;
Zn-3(BTC)(2);
12H(2)O;
Antimicrobial activity;
Sonication;
Silk;
METAL-ORGANIC FRAMEWORKS;
NANOPARTICLES;
ADSORPTION;
HYDROGEN;
SILVER;
MEMBRANES;
POLYMER;
STORAGE;
D O I:
10.1007/s10904-014-0101-5
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
A porous coordination polymer, Zn-3(BTC)(2)center dot 12H(2)O (Zn-BTC) upon silk yarn, has been synthesized under ultrasound irradiation of identical reaction mixtures of Zn(II) and H3BTC (BTC = 1,3,5-benzenetricarboxylate). Effects of temperature, sequential dipping steps and sonication on the growth of Zn-BTC upon silk yarn were investigated. These systems depicted a decrease in the particles size accompanying a decrease in the sequential dipping steps. Results showed a decrease in the particles size as decreasing frequency of ultrasound irradiation. The antimicrobial activity of Zn-BTC upon fiber was tested against the Gram positive strain Micrococcus sp. and Gram negative bacterial strain Escherichia coli. The samples were characterized with X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy spectra and scanning electron microscopy. XRPD analyses indicated that the prepared Zn-BTC nanostructures on silk fibers were crystalline.
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页码:1096 / 1102
页数:7
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