[(Z)-N-(3-Chlorophenyl)-O-ethylthiocarbamato-κS](triphenylphosphine-κP)gold(I)

被引：1

作者：

Tadbuppa, Primjira P. ^{[2
]}

Tiekink, Edward R. T. ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

CARBONIMIDOTHIOATES; PH;

D O I：

10.1107/S1600536809049551

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S, P-donor set [S-Au-P = 175.86 (3)degrees]. The deviation from linearity is ascribed to the proximate O atom derived from the thio-carbamato anion [Au center dot center dot center dot O = 2.967 (3) angstrom].

引用

页码：M1663 / U1419

页数：10

共 9 条

[1]

Beurskens P.T., 1992, The DIRDIF program system

[2]

Brandenburg K., 2006, DIAMOND

[3]

Bruker, 2000, SMART SAINT SADABS

[4] TRIORGANOPHOSPHINEGOLD(I) CARBONIMIDOTHIOATES [J].

HALL, VJ ;

SIASIOS, G ;

TIEKINK, ERT .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1993, 46 (04) :561-570

[5] Supramolecular aggregation patterns in the crystal structures of the dinuclear phosphinegold(I) thiolates, [(Ph2P(CH2)4PPh2){AuSC(OR) = NC6H4Y-4}2] for R = Me, Et or iPr and Y=H, NO2 or Me:: the influence on intermolecular interactions exerted by R and Y [J].

Ho, Soo Yei ;

Tiekink, Edward R. T. .

CRYSTENGCOMM, 2007, 9 (05) :368-378

[6] Luminescent phosphine gold(I) thiolates:: Correlation between crystal structure and photoluminescent properties in [R3PAu{SC(OMe)= NC6H4NO2-4}] (R = Et, Cy, Ph) and [(Ph2P-R-PPh2){AuSC(OMe)= NC6H4NO2-4}2] (R = CH2, (CH2)2, (CH2)3, (CH2)4, Fc) [J].

Ho, Soo Yei ;

Cheng, Eddie Chung-Chin ;

Tiekink, Edward R. T. ;

Yam, Vivian Wing-Wah .

INORGANIC CHEMISTRY, 2006, 45 (20) :8165-8174

[7] Electronic and steric control over Au••• Au, C-H••• O and C-H••• π interactions in the crystal structures of mononuclear triarylphosphinegold( I) carbonimidothioates:: R3PAu[SC(OMe) = NR′] for R′ = Ph, o-tol, m-tol or p-tol, and R′ = Ph, o-tol, m-tol, p-tol or C6H4NO2-4 [J].

Kuan, Fong Sheen ;

Ho, Soo Yei ;

Tadbuppa, Primjira P. ;

Tiekink, Edward R. T. .

CRYSTENGCOMM, 2008, 10 (05) :548-564

[8] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[9]

WESTRIP SP, 2009, PUBLCIF UNPUB

← 1 →