Ligand-tailored single-site silica supported titanium catalysts: Synthesis, characterization and towards cyanosilylation reaction

被引：7

作者：

Xu, Wei ^{[1
]}

Li, Yani ^{[1
]}

Yu, Bo ^{[1
]}

Yang, Jindou ^{[1
]}

Zhang, Ying ^{[1
]}

Chen, Xi ^{[1
]}

Zhang, Guofang ^{[1
]}

Gao, Ziwei ^{[1
]}

机构：

[1] Shaanxi Normal Univ, MOE Sch Chem & Chem Engn, Key Lab Appl Surface & Colloid Chem, Xian 710062, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2015年 / 221卷

基金：

中国国家自然科学基金;

关键词：

Surface organometallic chemistry; Silica; Surface titanium complex; Cyanosilylation; SURFACE ORGANOMETALLIC CHEMISTRY; HETEROGENEOUS CATALYSTS; MESOPOROUS SILICA; MOLECULAR-SIEVES; ACTIVE-SITES; TI; EPOXIDATION; METATHESIS; OXIDATION; ALKANES;

D O I：

10.1016/j.jssc.2014.10.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A successive anchoring of Ti(NMe2)(4), cyclopentadiene and a O-donor ligand, 1-hydroxyethylbenzene (PEA), 1,1'-bi-2-naphthol (Binol) or 2,3-dihydroxybutanedioic acid diethyl ester (Tartrate), on silica was conducted by SOMC strategy in moderate conditions. The silica, monitored by in-situ Fourier transform infrared spectroscopy (in-situ FT-IR), was pretreated at different temperatures (200, 500 and 800 degrees C). The ligand tailored silica-supported titanium complexes were characterized by in-situ FT-IR, C-13 CP MAS-NMR, X-ray photoelectron spectroscopy (XPS), X-ray absorption near edge structure (XANES) and elemental analysis in detail, verifying that the surface titanium species are single sited. The catalytic activity of the ligand tailored single-site silica supported titanium complexes was evaluated by a cyanosilylation of benzaldehyde. The results showed that the catalytic activity is dependent strongly on the dehydroxylation temperatures of silica and the configuration of the ligands. (C) 2014 Elsevier Inc. All rights reserved.

引用

页码：208 / 215

页数：8

共 51 条

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