Palladium-catalyzed desulfitative Sonogashira-Hagihara cross-couplings of arenesulfonyl chlorides and terminal alkynes

被引：67

作者：

Dubbaka, SR ^{[1
]}

Vogel, P ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, EPFL, BCH, Lab Glycochem & Asymmetr Synth, CH-1015 Lausanne, Switzerland

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 13-15期

关键词：

alkynes; arenesulfonyl chlorides; C-C cross coupling; homogeneous catalysis; palladium; tri(t-butyl)phosphine ligand;

D O I：

10.1002/adsc.200404146

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

For the first time, conditions have been found for the palladium-catalyzed desulfitative carbon-carbon cross-coupling of arenesulfonyl chlorides with aryl- and alkylacetylenes. Pd-2(dba)(3)/P(t-Bu)(3) and CuI provide the best catalyst for reactions in re-fluxing THF and in the presence of K2CO3.

引用

页码：1793 / 1797

页数：5

共 50 条

[11] Development of palladium-catalyzed migrative cross-couplings
Baudoin, Olivier
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
[12] Palladium-catalyzed micellar cross-couplings: An outlook
Ansari, Tharique N.
Gallou, Fabrice
Handa, Sachin
COORDINATION CHEMISTRY REVIEWS, 2023, 488
[13] Palladium-catalyzed Suzuki-Miyaura cross-couplings of sulfonyl chlorides and boronic acids
Dubbaka, SR
Vogel, P
ORGANIC LETTERS, 2004, 6 (01) : 95 - 98
[14] Palladium-Catalyzed Dehydrogenative Cross-Couplings of Benzazoles with Azoles
Han, Wei
Mayer, Peter
Ofial, Armin R.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (09) : 2178 - 2182
[15] Palladium-Catalyzed Selective Dehydrogenative Cross-Couplings of Heteroarenes
Bugaut, Xavier
Glorius, Frank
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (33) : 7479 - 7481
[16] NiXantphos: A Deprotonatable Ligand for Room-Temperature Palladium-Catalyzed Cross-Couplings of Aryl Chlorides
Zhang, Jiadi
Bellomo, Ana
Trongsiriwat, Nisalak
Jia, Tiezheng
Carroll, Patrick J.
Dreher, Spencer D.
Tudge, Matthew T.
Yin, Haolin
Robinson, Jerome R.
Schelter, Eric J.
Walsh, Patrick J.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (17) : 6276 - 6287
[17] Palladium-Catalyzed Decarbonylative Sonogashira Coupling of Terminal Alkynes with Carboxylic Acids
Li, Xinyi
Liu, Long
Huang, Tianzeng
Tang, Zhi
Li, Chunya
Li, Wenhui
Zhang, Tao
Li, Zhaohui
Chen, Tieqiao
ORGANIC LETTERS, 2021, 23 (09) : 3304 - 3309
[18] Palladium-catalyzed denitrative Sonogashira-type cross-coupling of nitrobenzenes with terminal alkynes
Feng, Boya
Yang, Yudong
You, Jingsong
CHEMICAL COMMUNICATIONS, 2020, 56 (05) : 790 - 793
[19] Three chemists share prize for palladium-catalyzed cross-couplings
不详
CHEMSUSCHEM, 2010, 3 (11) : 1224 - 1224
[20] Palladium-catalyzed Hiyama cross-couplings of aryl arenesulfonates with arylsilanes
Zhang, Liang
Wu, Jie
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (37) : 12250 - +

← 1 2 3 4 5 →