Poly(acrylamide-homocysteine thiolactone) as a synthetic platform for the preparation of polymeric ionic liquids by post ring-opening-orthogonal modifications

被引:23
作者
Montolio, Silvia [1 ]
Zagorodko, Oleksandr [2 ]
Porcar, Raul [2 ]
Isabel Burguete, M. [2 ]
Luis, Santiago V. [2 ]
Tenhu, Heikki [1 ]
Garcia-Verdugo, Eduardo [1 ,2 ]
机构
[1] Univ Helsinki, Dept Chem, Helsinki, Finland
[2] Univ Jaume 1, Dept Quim Inorgan & Organ, E-12071 Castellon De La Plana, Spain
关键词
POT DOUBLE MODIFICATION; POLY(IONIC LIQUID)S; CHEMISTRY; NANOFIBERS; FUNCTIONALIZATION; SCIENCE; TOOL;
D O I
10.1039/c7py01067b
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(Acrylamide-Homocysteine Thiolactone) (PAHT) obtained by RAFT polymerisation can be used as a starting material for the synthesis, through its post modification, of a variety of advanced polymeric materials with different morphologies and a significant structural diversity. The examples here presented illustrate the utility of this approach for the preparation of functionalised polymers containing Ionic Liquid-like units (IL-like). These Polymeric Ionic Liquids (PILs) can be designed and obtained with a careful control of their structural elements according to the needs for a specific application.
引用
收藏
页码:4789 / 4797
页数:9
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